n-Butyllithium Catalyzed Hydroboration of Nitriles and Carbodiimides

Ben Yan; Xing He; Congjian Ni; Zhi Yang; Xiaoli Ma

doi:10.1002/cctc.202001669

n-Butyllithium Catalyzed Hydroboration of Nitriles and Carbodiimides

Ben Yan, Xing He, Congjian Ni, Zhi Yang^*, Xiaoli Ma^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Highly efficient and selective hydroboration of nitriles and carbodiimides with pinacolborane (HBpin) is achieved by using the simple and convenient n-BuLi as a catalyst. Solvent-free and good functional group tolerance under mild conditions have been achieved. A possible mechanistic pathway of the n-BuLi catalyzed hydroboration of nitriles with HBpin is proposed.

Original language	English
Pages (from-to)	851-854
Number of pages	4
Journal	ChemCatChem
Volume	13
Issue number	3
DOIs	https://doi.org/10.1002/cctc.202001669
Publication status	Published - 5 Feb 2021

Keywords

carbodiimides
hydroboration
n-Butyllithium
nitriles

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10.1002/cctc.202001669

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abstract = "Highly efficient and selective hydroboration of nitriles and carbodiimides with pinacolborane (HBpin) is achieved by using the simple and convenient n-BuLi as a catalyst. Solvent-free and good functional group tolerance under mild conditions have been achieved. A possible mechanistic pathway of the n-BuLi catalyzed hydroboration of nitriles with HBpin is proposed.",

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author = "Ben Yan and Xing He and Congjian Ni and Zhi Yang and Xiaoli Ma",

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AU - Yan, Ben

AU - He, Xing

AU - Ni, Congjian

AU - Yang, Zhi

AU - Ma, Xiaoli

PY - 2021/2/5

Y1 - 2021/2/5

N2 - Highly efficient and selective hydroboration of nitriles and carbodiimides with pinacolborane (HBpin) is achieved by using the simple and convenient n-BuLi as a catalyst. Solvent-free and good functional group tolerance under mild conditions have been achieved. A possible mechanistic pathway of the n-BuLi catalyzed hydroboration of nitriles with HBpin is proposed.

AB - Highly efficient and selective hydroboration of nitriles and carbodiimides with pinacolborane (HBpin) is achieved by using the simple and convenient n-BuLi as a catalyst. Solvent-free and good functional group tolerance under mild conditions have been achieved. A possible mechanistic pathway of the n-BuLi catalyzed hydroboration of nitriles with HBpin is proposed.

KW - carbodiimides

KW - hydroboration

KW - n-Butyllithium

KW - nitriles

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ER -

n-Butyllithium Catalyzed Hydroboration of Nitriles and Carbodiimides

Abstract

Keywords

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