Multinuclear Alkali Metal Complexes of a Triphenylene-Based Hexamine and the Transmetalation to Tris(N-heterocyclic tetrylenes) (Ge, Sn, Pb)

Fei Zhong; Xiaodong Yang; Lingyi Shen; Yanxia Zhao; Hongwei Ma; Biao Wu; Xiao Juan Yang

doi:10.1021/acs.inorgchem.6b01743

Multinuclear Alkali Metal Complexes of a Triphenylene-Based Hexamine and the Transmetalation to Tris(N-heterocyclic tetrylenes) (Ge, Sn, Pb)

Fei Zhong, Xiaodong Yang, Lingyi Shen, Yanxia Zhao, Hongwei Ma, Biao Wu, Xiao Juan Yang^*

^*Corresponding author for this work

School of Automation

Northwest University China

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

A C₃-symmetric hexamine (LH₆) based on the triphenylene and ortho-phenylenediamine (PDAH₂) skeletons has been synthesized, and was partially or fully deprotonated upon treatment with alkali metal agents to afford amino-amido or diamido coordination sites. Four alkali metal complexes, the dinuclear [Na₂(LH₄)(DME)₅] (1) and [K₂(LH₄)(DME)₄] (2), trinuclear [K₃(LH₃)(DME)₆] (3), and hexanuclear [Li₆(L)(DME)₆] (4), were obtained and used in transmetalation/ligand exchange with other metals. The hexalithium salt of the fully deprotonated ligand, [Li₆L], reacted with heavier group 14 element halides to yield three tris(N-heterocyclic tetrylenes), the germylene [Ge₃(L)] (5), stannylene [Sn₃(L)] (6), and plumbylene [Pb₃(L)] (7). The synthesis and crystal and electronic structures of these compounds are reported.

Original language	English
Pages (from-to)	9112-9120
Number of pages	9
Journal	Inorganic Chemistry
Volume	55
Issue number	17
DOIs	https://doi.org/10.1021/acs.inorgchem.6b01743
Publication status	Published - 6 Sept 2016

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title = "Multinuclear Alkali Metal Complexes of a Triphenylene-Based Hexamine and the Transmetalation to Tris(N-heterocyclic tetrylenes) (Ge, Sn, Pb)",

abstract = "A C3-symmetric hexamine (LH6) based on the triphenylene and ortho-phenylenediamine (PDAH2) skeletons has been synthesized, and was partially or fully deprotonated upon treatment with alkali metal agents to afford amino-amido or diamido coordination sites. Four alkali metal complexes, the dinuclear [Na2(LH4)(DME)5] (1) and [K2(LH4)(DME)4] (2), trinuclear [K3(LH3)(DME)6] (3), and hexanuclear [Li6(L)(DME)6] (4), were obtained and used in transmetalation/ligand exchange with other metals. The hexalithium salt of the fully deprotonated ligand, [Li6L], reacted with heavier group 14 element halides to yield three tris(N-heterocyclic tetrylenes), the germylene [Ge3(L)] (5), stannylene [Sn3(L)] (6), and plumbylene [Pb3(L)] (7). The synthesis and crystal and electronic structures of these compounds are reported.",

author = "Fei Zhong and Xiaodong Yang and Lingyi Shen and Yanxia Zhao and Hongwei Ma and Biao Wu and Yang, {Xiao Juan}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = sep,

day = "6",

doi = "10.1021/acs.inorgchem.6b01743",

language = "English",

volume = "55",

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T1 - Multinuclear Alkali Metal Complexes of a Triphenylene-Based Hexamine and the Transmetalation to Tris(N-heterocyclic tetrylenes) (Ge, Sn, Pb)

AU - Zhong, Fei

AU - Yang, Xiaodong

AU - Shen, Lingyi

AU - Zhao, Yanxia

AU - Ma, Hongwei

AU - Wu, Biao

AU - Yang, Xiao Juan

PY - 2016/9/6

Y1 - 2016/9/6

N2 - A C3-symmetric hexamine (LH6) based on the triphenylene and ortho-phenylenediamine (PDAH2) skeletons has been synthesized, and was partially or fully deprotonated upon treatment with alkali metal agents to afford amino-amido or diamido coordination sites. Four alkali metal complexes, the dinuclear [Na2(LH4)(DME)5] (1) and [K2(LH4)(DME)4] (2), trinuclear [K3(LH3)(DME)6] (3), and hexanuclear [Li6(L)(DME)6] (4), were obtained and used in transmetalation/ligand exchange with other metals. The hexalithium salt of the fully deprotonated ligand, [Li6L], reacted with heavier group 14 element halides to yield three tris(N-heterocyclic tetrylenes), the germylene [Ge3(L)] (5), stannylene [Sn3(L)] (6), and plumbylene [Pb3(L)] (7). The synthesis and crystal and electronic structures of these compounds are reported.

AB - A C3-symmetric hexamine (LH6) based on the triphenylene and ortho-phenylenediamine (PDAH2) skeletons has been synthesized, and was partially or fully deprotonated upon treatment with alkali metal agents to afford amino-amido or diamido coordination sites. Four alkali metal complexes, the dinuclear [Na2(LH4)(DME)5] (1) and [K2(LH4)(DME)4] (2), trinuclear [K3(LH3)(DME)6] (3), and hexanuclear [Li6(L)(DME)6] (4), were obtained and used in transmetalation/ligand exchange with other metals. The hexalithium salt of the fully deprotonated ligand, [Li6L], reacted with heavier group 14 element halides to yield three tris(N-heterocyclic tetrylenes), the germylene [Ge3(L)] (5), stannylene [Sn3(L)] (6), and plumbylene [Pb3(L)] (7). The synthesis and crystal and electronic structures of these compounds are reported.

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DO - 10.1021/acs.inorgchem.6b01743

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SN - 0020-1669

VL - 55

SP - 9112

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 17

ER -

Multinuclear Alkali Metal Complexes of a Triphenylene-Based Hexamine and the Transmetalation to Tris(N-heterocyclic tetrylenes) (Ge, Sn, Pb)

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