TY - JOUR
T1 - Mixed oxides derived from Cu-Co layered double hydroxide nanorods
T2 - Preparation, characterization and their catalytic activities
AU - Liu, Hongbo
AU - Jiao, Qingze
AU - Zhao, Yun
AU - Li, Hansheng
AU - Sun, Chongbo
AU - Li, Xuefei
PY - 2010/4/30
Y1 - 2010/4/30
N2 - In the present work, a series of Cu-Co layered double hydroxide (LDH) nanorods were prepared using a co-precipitation reaction with hydrothermal treatment for the first time. Mixed oxides obtained by calcination of Cu-Co LDHs (Cu-Co CLDHs) were used as new catalysts for promoting thermal decomposition of ammonium perchlorate (AP). The catalytic activities were investigated by differential thermal analysis (DTA). Thermal decomposition temperature of AP was considerably decreased in the presence of Cu-Co CLDHs. Cu-Co CLDHs exhibit higher catalytic activity than the mechanical mixture of CuO and Co2O3. The catalytic mechanism was also briefly discussed.
AB - In the present work, a series of Cu-Co layered double hydroxide (LDH) nanorods were prepared using a co-precipitation reaction with hydrothermal treatment for the first time. Mixed oxides obtained by calcination of Cu-Co LDHs (Cu-Co CLDHs) were used as new catalysts for promoting thermal decomposition of ammonium perchlorate (AP). The catalytic activities were investigated by differential thermal analysis (DTA). Thermal decomposition temperature of AP was considerably decreased in the presence of Cu-Co CLDHs. Cu-Co CLDHs exhibit higher catalytic activity than the mechanical mixture of CuO and Co2O3. The catalytic mechanism was also briefly discussed.
KW - Ammonium perchlorate
KW - Cu-Co layered double hydroxide
KW - Nanorods
KW - Thermal decomposition
UR - http://www.scopus.com/inward/record.url?scp=77950861934&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2010.02.004
DO - 10.1016/j.jallcom.2010.02.004
M3 - Article
AN - SCOPUS:77950861934
SN - 0925-8388
VL - 496
SP - 317
EP - 323
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
IS - 1-2
ER -