Mg-Mg-bonded compounds with N,N′-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands

Meimei Ma; Huanhuan Wang; Juju Wang; Lingyi Shen; Yanxia Zhao; Wen Hua Xu; Biao Wu; Xiao Juan Yang

doi:10.1039/c9dt00028c

Mg-Mg-bonded compounds with N,N′-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands

Meimei Ma, Huanhuan Wang, Juju Wang, Lingyi Shen, Yanxia Zhao, Wen Hua Xu, Biao Wu, Xiao Juan Yang^*

^*Corresponding author for this work

Northwest University China

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Two Mg-Mg-bonded compounds were synthesized by using the ligands N,N′-bis(dipp)-phenanthrene-9,10-diimine (L ² ) and N,N′-bis(dipp)-o-phenylenediamine (H ₂ L ³ ; dipp = 2,6-diisopropylphenyl). These new Mg(i) species were characterized by X-ray diffraction, NMR, UV-Vis and fluorescence spectroscopy, and DFT computations. Their reactions with unsaturated organic molecules were examined.

Original language	English
Pages (from-to)	2295-2299
Number of pages	5
Journal	Dalton Transactions
Volume	48
Issue number	7
DOIs	https://doi.org/10.1039/c9dt00028c
Publication status	Published - 2019
Externally published	Yes

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title = "Mg-Mg-bonded compounds with N,N′-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands",

abstract = " Two Mg-Mg-bonded compounds were synthesized by using the ligands N,N′-bis(dipp)-phenanthrene-9,10-diimine (L 2 ) and N,N′-bis(dipp)-o-phenylenediamine (H 2 L 3 ; dipp = 2,6-diisopropylphenyl). These new Mg(i) species were characterized by X-ray diffraction, NMR, UV-Vis and fluorescence spectroscopy, and DFT computations. Their reactions with unsaturated organic molecules were examined.",

author = "Meimei Ma and Huanhuan Wang and Juju Wang and Lingyi Shen and Yanxia Zhao and Xu, {Wen Hua} and Biao Wu and Yang, {Xiao Juan}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9dt00028c",

language = "English",

volume = "48",

pages = "2295--2299",

journal = "Dalton Transactions",

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TY - JOUR

T1 - Mg-Mg-bonded compounds with N,N′-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands

AU - Ma, Meimei

AU - Wang, Huanhuan

AU - Wang, Juju

AU - Shen, Lingyi

AU - Zhao, Yanxia

AU - Xu, Wen Hua

AU - Wu, Biao

AU - Yang, Xiao Juan

PY - 2019

Y1 - 2019

N2 - Two Mg-Mg-bonded compounds were synthesized by using the ligands N,N′-bis(dipp)-phenanthrene-9,10-diimine (L 2 ) and N,N′-bis(dipp)-o-phenylenediamine (H 2 L 3 ; dipp = 2,6-diisopropylphenyl). These new Mg(i) species were characterized by X-ray diffraction, NMR, UV-Vis and fluorescence spectroscopy, and DFT computations. Their reactions with unsaturated organic molecules were examined.

AB - Two Mg-Mg-bonded compounds were synthesized by using the ligands N,N′-bis(dipp)-phenanthrene-9,10-diimine (L 2 ) and N,N′-bis(dipp)-o-phenylenediamine (H 2 L 3 ; dipp = 2,6-diisopropylphenyl). These new Mg(i) species were characterized by X-ray diffraction, NMR, UV-Vis and fluorescence spectroscopy, and DFT computations. Their reactions with unsaturated organic molecules were examined.

UR - http://www.scopus.com/inward/record.url?scp=85061374252&partnerID=8YFLogxK

U2 - 10.1039/c9dt00028c

DO - 10.1039/c9dt00028c

M3 - Article

C2 - 30681693

AN - SCOPUS:85061374252

SN - 1477-9226

VL - 48

SP - 2295

EP - 2299

JO - Dalton Transactions

JF - Dalton Transactions

IS - 7

ER -

Mg-Mg-bonded compounds with N,N′-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands

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