Metal-oxo cluster-supported transition metal complexes: Hydrothermal synthesis and characterization of [{M(phen)2}2(Mo8O26)] (M = Ni or Co)

Ji Qing Xu; Ren Zhang Wang; Guo Yu Yang; Yong Heng Xing; Dong Mei Li; Wei Ming Bu; Ling Ye; Yu Guo Fan; Guang Di Yang; Yan Xing; Yong Hua Lin; Heng Qing Jia

doi:10.1039/a900643e

Metal-oxo cluster-supported transition metal complexes: Hydrothermal synthesis and characterization of [{M(phen)₂}₂(Mo₈O₂₆)] (M = Ni or Co)

Ji Qing Xu^*, Ren Zhang Wang, Guo Yu Yang, Yong Heng Xing, Dong Mei Li, Wei Ming Bu, Ling Ye, Yu Guo Fan, Guang Di Yang, Yan Xing, Yong Hua Lin, Heng Qing Jia

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

146 Citations (Scopus)

Abstract

Two new metal-oxo supported transition metal complexes, [{M(phen)₂}₂(Mo₈O₂₆) (M = Ni or Co; phen = 1,10-phenanthroline) are synthesized by a hydrothermal method and characterized by X-ray crystallography, showing that the octamolybdate possesses a novel unprecedented structure and that [M(phen)₂]²⁺ units are covalently bonded to the [Mo₈O₂₆]^4- cluster.

Original language	English
Pages (from-to)	983-984
Number of pages	2
Journal	Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/a900643e
Publication status	Published - 7 Jun 1999
Externally published	Yes

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Xu, J. Q., Wang, R. Z., Yang, G. Y., Xing, Y. H., Li, D. M., Bu, W. M., Ye, L., Fan, Y. G., Yang, G. D., Xing, Y., Lin, Y. H., & Jia, H. Q. (1999). Metal-oxo cluster-supported transition metal complexes: Hydrothermal synthesis and characterization of [{M(phen)₂}₂(Mo₈O₂₆)] (M = Ni or Co). Chemical Communications, (11), 983-984. https://doi.org/10.1039/a900643e

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abstract = "Two new metal-oxo supported transition metal complexes, [{M(phen)2}2(Mo8O26) (M = Ni or Co; phen = 1,10-phenanthroline) are synthesized by a hydrothermal method and characterized by X-ray crystallography, showing that the octamolybdate possesses a novel unprecedented structure and that [M(phen)2]2+ units are covalently bonded to the [Mo8O26]4- cluster.",

author = "Xu, {Ji Qing} and Wang, {Ren Zhang} and Yang, {Guo Yu} and Xing, {Yong Heng} and Li, {Dong Mei} and Bu, {Wei Ming} and Ling Ye and Fan, {Yu Guo} and Yang, {Guang Di} and Yan Xing and Lin, {Yong Hua} and Jia, {Heng Qing}",

year = "1999",

month = jun,

day = "7",

doi = "10.1039/a900643e",

language = "English",

pages = "983--984",

journal = "Chemical Communications",

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T2 - Hydrothermal synthesis and characterization of [{M(phen)2}2(Mo8O26)] (M = Ni or Co)

AU - Xu, Ji Qing

AU - Wang, Ren Zhang

AU - Yang, Guo Yu

AU - Xing, Yong Heng

AU - Li, Dong Mei

AU - Bu, Wei Ming

AU - Ye, Ling

AU - Fan, Yu Guo

AU - Yang, Guang Di

AU - Xing, Yan

AU - Lin, Yong Hua

AU - Jia, Heng Qing

PY - 1999/6/7

Y1 - 1999/6/7

N2 - Two new metal-oxo supported transition metal complexes, [{M(phen)2}2(Mo8O26) (M = Ni or Co; phen = 1,10-phenanthroline) are synthesized by a hydrothermal method and characterized by X-ray crystallography, showing that the octamolybdate possesses a novel unprecedented structure and that [M(phen)2]2+ units are covalently bonded to the [Mo8O26]4- cluster.

AB - Two new metal-oxo supported transition metal complexes, [{M(phen)2}2(Mo8O26) (M = Ni or Co; phen = 1,10-phenanthroline) are synthesized by a hydrothermal method and characterized by X-ray crystallography, showing that the octamolybdate possesses a novel unprecedented structure and that [M(phen)2]2+ units are covalently bonded to the [Mo8O26]4- cluster.

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U2 - 10.1039/a900643e

DO - 10.1039/a900643e

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JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

Metal-oxo cluster-supported transition metal complexes: Hydrothermal synthesis and characterization of [{M(phen)₂}₂(Mo₈O₂₆)] (M = Ni or Co)

Abstract

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