LiB9O15·H2dap·H2O: A Cotemplated Acentric Layer-Pillared Borate Built by Mixed Oxoboron Clusters

Xu Yan Li; Guo Yu Yang

doi:10.1021/acs.inorgchem.1c02784

LiB₉O₁₅·H₂dap·H₂O: A Cotemplated Acentric Layer-Pillared Borate Built by Mixed Oxoboron Clusters

Xu Yan Li, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

An acentric layer-pillared borate, LiB9O15·H2dap·H2O (1, dap = 1,3-diaminopropane), cotemplated by organic and inorganic cations and build by mixed oxoboron cluster units of B6O138- and B3O75-, has first been made under solvothermal conditions, in which the B6O138- clusters link each other to form 2D layers containing 9-membered ring (MR) windows, while the B3O75- clusters join together to produce 1D chains that further perform as the pillars to connect neighboring layers, resulting in a 3D layer-pillared framework with 13- and 7-MR channels located by H2dap2+ and Li+ cations, respectively. Its second harmonic generation shows a response of ∼2.1 times that of KDP (KH2PO4).

Original language	English
Pages (from-to)	16085-16089
Number of pages	5
Journal	Inorganic Chemistry
Volume	60
Issue number	21
DOIs	https://doi.org/10.1021/acs.inorgchem.1c02784
Publication status	Published - 1 Nov 2021

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title = "LiB9O15·H2dap·H2O: A Cotemplated Acentric Layer-Pillared Borate Built by Mixed Oxoboron Clusters",

abstract = "An acentric layer-pillared borate, LiB9O15·H2dap·H2O (1, dap = 1,3-diaminopropane), cotemplated by organic and inorganic cations and build by mixed oxoboron cluster units of B6O138- and B3O75-, has first been made under solvothermal conditions, in which the B6O138- clusters link each other to form 2D layers containing 9-membered ring (MR) windows, while the B3O75- clusters join together to produce 1D chains that further perform as the pillars to connect neighboring layers, resulting in a 3D layer-pillared framework with 13- and 7-MR channels located by H2dap2+ and Li+ cations, respectively. Its second harmonic generation shows a response of ∼2.1 times that of KDP (KH2PO4).",

author = "Li, {Xu Yan} and Yang, {Guo Yu}",

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doi = "10.1021/acs.inorgchem.1c02784",

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PY - 2021/11/1

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N2 - An acentric layer-pillared borate, LiB9O15·H2dap·H2O (1, dap = 1,3-diaminopropane), cotemplated by organic and inorganic cations and build by mixed oxoboron cluster units of B6O138- and B3O75-, has first been made under solvothermal conditions, in which the B6O138- clusters link each other to form 2D layers containing 9-membered ring (MR) windows, while the B3O75- clusters join together to produce 1D chains that further perform as the pillars to connect neighboring layers, resulting in a 3D layer-pillared framework with 13- and 7-MR channels located by H2dap2+ and Li+ cations, respectively. Its second harmonic generation shows a response of ∼2.1 times that of KDP (KH2PO4).

AB - An acentric layer-pillared borate, LiB9O15·H2dap·H2O (1, dap = 1,3-diaminopropane), cotemplated by organic and inorganic cations and build by mixed oxoboron cluster units of B6O138- and B3O75-, has first been made under solvothermal conditions, in which the B6O138- clusters link each other to form 2D layers containing 9-membered ring (MR) windows, while the B3O75- clusters join together to produce 1D chains that further perform as the pillars to connect neighboring layers, resulting in a 3D layer-pillared framework with 13- and 7-MR channels located by H2dap2+ and Li+ cations, respectively. Its second harmonic generation shows a response of ∼2.1 times that of KDP (KH2PO4).

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LiB₉O₁₅·H₂dap·H₂O: A Cotemplated Acentric Layer-Pillared Borate Built by Mixed Oxoboron Clusters

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