Lanthanide-Anderson Polyoxometalates Frameworks: Efficient Sulfide Photooxidation

De Gang Ke; Sheng Li Huang; Guo Yu Yang

doi:10.1021/acs.inorgchem.2c03504

Lanthanide-Anderson Polyoxometalates Frameworks: Efficient Sulfide Photooxidation

De Gang Ke, Sheng Li Huang^*, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Three polyoxometalate-based metal-organic frameworks were synthesized by the thermal reaction of pyridyl-Anderson polyoxometalate linker and lanthanide ions. With the help of [Ru(bpy)₃]²⁺photosensitizer, these frameworks exhibited excellent photocatalytic sulfide oxidation performance with sulfoxide selectivity. The reactive oxygen species as well as the photooxidation mechanism were also explored.

Original language	English
Pages (from-to)	20080-20086
Number of pages	7
Journal	Inorganic Chemistry
Volume	61
Issue number	49
DOIs	https://doi.org/10.1021/acs.inorgchem.2c03504
Publication status	Published - 12 Dec 2022

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title = "Lanthanide-Anderson Polyoxometalates Frameworks: Efficient Sulfide Photooxidation",

abstract = "Three polyoxometalate-based metal-organic frameworks were synthesized by the thermal reaction of pyridyl-Anderson polyoxometalate linker and lanthanide ions. With the help of [Ru(bpy)3]2+photosensitizer, these frameworks exhibited excellent photocatalytic sulfide oxidation performance with sulfoxide selectivity. The reactive oxygen species as well as the photooxidation mechanism were also explored.",

author = "Ke, {De Gang} and Huang, {Sheng Li} and Yang, {Guo Yu}",

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T2 - Efficient Sulfide Photooxidation

AU - Ke, De Gang

AU - Huang, Sheng Li

AU - Yang, Guo Yu

PY - 2022/12/12

Y1 - 2022/12/12

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AB - Three polyoxometalate-based metal-organic frameworks were synthesized by the thermal reaction of pyridyl-Anderson polyoxometalate linker and lanthanide ions. With the help of [Ru(bpy)3]2+photosensitizer, these frameworks exhibited excellent photocatalytic sulfide oxidation performance with sulfoxide selectivity. The reactive oxygen species as well as the photooxidation mechanism were also explored.

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DO - 10.1021/acs.inorgchem.2c03504

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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Lanthanide-Anderson Polyoxometalates Frameworks: Efficient Sulfide Photooxidation

Abstract

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