Hydrothermal synthesis, crystal structure and characterization of [Zn(H2O)4]2 [H2As6V 15O42(H2O)]·2H2O

Xiao Bing Cui; Ji Qing Xu; Lan Ding; Hong Ding; Ling Ye; Guo Yu Yang

doi:10.1016/j.molstruc.2003.08.014

Hydrothermal synthesis, crystal structure and characterization of [Zn(H₂O)₄]₂ [H₂As₆V ₁₅O₄₂(H₂O)]·2H₂O

Xiao Bing Cui, Ji Qing Xu^*, Lan Ding, Hong Ding, Ling Ye, Guo Yu Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The compound [Zn(H₂O)₄]₂[H ₂As₆V₁₅O₄₂(H₂O)]· 2H₂O (1) has been synthesized and characterized by elemental analysis, IR, ESR, magnetic measurement, third-order nonlinear property study and single crystal X-ray diffraction analysis. The compound 1 crystallizes in trigonal space group R3, a = b = 12.0601(17) Å, c = 33.970(7) Å, γ = 120°, V = 4278.8(12) Å³, Z = 3 and R1(wR2) = 0.0512 (0.1171). The crystal structure is constructed from [H₂As ₆V₁₅O₄₂(H₂O)]^4- anions and [Zn(H₂O)₄]²⁺ cations linked through hydrogen bonds into a network. The [H₂As₆V ₁₅O₄₂(H₂O)]^6- cluster consists of 15 VO₅ square pyramids linked by three As₂O₅ handle-like units.

Original language	English
Pages (from-to)	131-137
Number of pages	7
Journal	Journal of Molecular Structure
Volume	660
Issue number	1-3
DOIs	https://doi.org/10.1016/j.molstruc.2003.08.014
Publication status	Published - 12 Nov 2003
Externally published	Yes

Keywords

Arsenic
Arsenic-vanadium cluster
Cluster
Crystal structure
Hydrogen bond
Hydrothermal synthesis
Polyoxometalate
Vanadium

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10.1016/j.molstruc.2003.08.014

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@article{a7a73a1afc32428d9a8b274414457842,

title = "Hydrothermal synthesis, crystal structure and characterization of [Zn(H2O)4]2 [H2As6V 15O42(H2O)]·2H2O",

abstract = "The compound [Zn(H2O)4]2[H 2As6V15O42(H2O)]· 2H2O (1) has been synthesized and characterized by elemental analysis, IR, ESR, magnetic measurement, third-order nonlinear property study and single crystal X-ray diffraction analysis. The compound 1 crystallizes in trigonal space group R3, a = b = 12.0601(17) {\AA}, c = 33.970(7) {\AA}, γ = 120°, V = 4278.8(12) {\AA}3, Z = 3 and R1(wR2) = 0.0512 (0.1171). The crystal structure is constructed from [H2As 6V15O42(H2O)]4- anions and [Zn(H2O)4]2+ cations linked through hydrogen bonds into a network. The [H2As6V 15O42(H2O)]6- cluster consists of 15 VO5 square pyramids linked by three As2O5 handle-like units.",

keywords = "Arsenic, Arsenic-vanadium cluster, Cluster, Crystal structure, Hydrogen bond, Hydrothermal synthesis, Polyoxometalate, Vanadium",

author = "Cui, {Xiao Bing} and Xu, {Ji Qing} and Lan Ding and Hong Ding and Ling Ye and Yang, {Guo Yu}",

year = "2003",

month = nov,

day = "12",

doi = "10.1016/j.molstruc.2003.08.014",

language = "English",

volume = "660",

pages = "131--137",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

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T1 - Hydrothermal synthesis, crystal structure and characterization of [Zn(H2O)4]2 [H2As6V 15O42(H2O)]·2H2O

AU - Cui, Xiao Bing

AU - Xu, Ji Qing

AU - Ding, Lan

AU - Ding, Hong

AU - Ye, Ling

AU - Yang, Guo Yu

PY - 2003/11/12

Y1 - 2003/11/12

N2 - The compound [Zn(H2O)4]2[H 2As6V15O42(H2O)]· 2H2O (1) has been synthesized and characterized by elemental analysis, IR, ESR, magnetic measurement, third-order nonlinear property study and single crystal X-ray diffraction analysis. The compound 1 crystallizes in trigonal space group R3, a = b = 12.0601(17) Å, c = 33.970(7) Å, γ = 120°, V = 4278.8(12) Å3, Z = 3 and R1(wR2) = 0.0512 (0.1171). The crystal structure is constructed from [H2As 6V15O42(H2O)]4- anions and [Zn(H2O)4]2+ cations linked through hydrogen bonds into a network. The [H2As6V 15O42(H2O)]6- cluster consists of 15 VO5 square pyramids linked by three As2O5 handle-like units.

AB - The compound [Zn(H2O)4]2[H 2As6V15O42(H2O)]· 2H2O (1) has been synthesized and characterized by elemental analysis, IR, ESR, magnetic measurement, third-order nonlinear property study and single crystal X-ray diffraction analysis. The compound 1 crystallizes in trigonal space group R3, a = b = 12.0601(17) Å, c = 33.970(7) Å, γ = 120°, V = 4278.8(12) Å3, Z = 3 and R1(wR2) = 0.0512 (0.1171). The crystal structure is constructed from [H2As 6V15O42(H2O)]4- anions and [Zn(H2O)4]2+ cations linked through hydrogen bonds into a network. The [H2As6V 15O42(H2O)]6- cluster consists of 15 VO5 square pyramids linked by three As2O5 handle-like units.

KW - Arsenic

KW - Arsenic-vanadium cluster

KW - Cluster

KW - Crystal structure

KW - Hydrogen bond

KW - Hydrothermal synthesis

KW - Polyoxometalate

KW - Vanadium

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U2 - 10.1016/j.molstruc.2003.08.014

DO - 10.1016/j.molstruc.2003.08.014

M3 - Article

AN - SCOPUS:0142152483

SN - 0022-2860

VL - 660

SP - 131

EP - 137

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Hydrothermal synthesis, crystal structure and characterization of [Zn(H₂O)₄]₂ [H₂As₆V ₁₅O₄₂(H₂O)]·2H₂O

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Keywords

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