TY - JOUR
T1 - Hydrothermal synthesis and crystal structure of a new dinuclear copper complex
T2 - [Cu2(Ophen)2]·2H2O (HOphen=2-Hydroxy-1,10-phenanthroline)
AU - Hu, Chang Wen
AU - Wang, Chun Xiu
AU - Li, Hui
AU - He, Yan Ting
AU - Gong, Yun
PY - 2005/12
Y1 - 2005/12
N2 - A new dinuclear copper complex: [Cu2(Ophen)2]·2H2O (HOphen=2-hydroxy-1,10-phenanthroline) was hydrothermally synthesized and its structure characterized through IR spectra and single crystal X-ray diffraction analysis. Crystal data: Orthorhombic, α=0.3842(5) nm, b=1.913(3) nm, c=2.691(3) nm, α=β=γ=90.00°, Z=2, V=1.978(4) nm3, Dc=1.344 mg/m3, R1=0.0839, wR1=0.1471. The ligand 2-hydroxy-1,10-phenanthroline comes from the hydroxylation of phenanthroline. There are two solvent water molecules in the compound.
AB - A new dinuclear copper complex: [Cu2(Ophen)2]·2H2O (HOphen=2-hydroxy-1,10-phenanthroline) was hydrothermally synthesized and its structure characterized through IR spectra and single crystal X-ray diffraction analysis. Crystal data: Orthorhombic, α=0.3842(5) nm, b=1.913(3) nm, c=2.691(3) nm, α=β=γ=90.00°, Z=2, V=1.978(4) nm3, Dc=1.344 mg/m3, R1=0.0839, wR1=0.1471. The ligand 2-hydroxy-1,10-phenanthroline comes from the hydroxylation of phenanthroline. There are two solvent water molecules in the compound.
KW - Crystal structure
KW - Cu(I) complex
KW - Hydrothermal synthesis
KW - Hydroxylation of phenanthroline
UR - http://www.scopus.com/inward/record.url?scp=33644837874&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:33644837874
SN - 1001-0645
VL - 25
SP - 1103-1105+1112
JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
IS - 12
ER -