Abstract
A new compound [As8IIIV14IVO42 (CO3)][Cu(en)2]3·10H2O (1) has been synthesized from V2O5, As2O3, CuCl2·2H2O, en and H2C2O4·2H2O in aqueous solution using the hydrothermal metho d and characterized by single-crystal X-ray diffraction analysis. X-ray crystallography reveals that 1 is a novel two-dimensional framework material constructed from the mixed As/V polyoxometalates and coordination groups.
Original language | English |
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Pages (from-to) | 259-261 |
Number of pages | 3 |
Journal | Inorganic Chemistry Communications |
Volume | 6 |
Issue number | 3 |
DOIs | |
Publication status | Published - 1 Mar 2003 |
Externally published | Yes |
Keywords
- As/V/O polyoxometalates
- Coordination groups
- Crystal structure
- Hydrothermal synthesis
- Two-dimensional structure