Abstract
Three complexes, [M(CO)5Tz], have been synthesised by the photochemical reaction of 3,5-dimethyl-1,2,4-triazole (Tz) with [M(CO) 6] (M = Cr, Mo and W). The crystal structure of [Cr(CO) 5Tz] has been characterised by X-ray analysis, and the 4H-tautomer of the triazole ligand is observed in this complex in the solid state.
Original language | English |
---|---|
Pages (from-to) | 495-496 |
Number of pages | 2 |
Journal | Journal of Chemical Research - Part S |
Issue number | 8 |
Publication status | Published - Aug 2003 |
Keywords
- 3,5-dimethyl-1,2,4-triazole
- Group 6 carbonyl complexes