Facile synthesis of novel cobalt particles by reduction method and their microwave absorption properties

Three kinds of cobalt particles with different morphologies and crystal structures were synthesized via reducing cobaltous sulfate (CoSO₄·7H₂O) by hydrazine hydrate (N₂H₄·H₂O) under ultrasonic wave, in which seignette salt (C₄H₄KNaO₆·4H₂O) or C₆O₇H₅Na₃·2H₂O acted as complexing agent, C₁₆H₃₃(CH₃)₃NBr acted as surfactant agent and sodium hydroxide (NaOH) acted as pH regulator. Less saturation magnetization and more coercivity were obtained compared to single hcp-cobalt and bulk cobalt, respectively. The electromagnetic properties of cobalt particles dispersed in paraffin (70wt.%) were measured in the microwave frequency range of 1-18GHz. The three kinds of cobalt particles all have multi-nonlinear dielectric resonances due to atomic and electronic polarization. The cobalt particles composed by nanosheets exhibit higher real part of permeability in the range of 10-18GHz compared to spherical cobalt particles. The reflection loss values of cobalt particles were calculated according to the transmission-line theory, and the minimal reflection loss of -19.06dB at 17.42GHz was observed corresponding to a thickness of 5mm.