Dissolution properties of 5,5′-bistetrazole-1, 1′-dihydroxy and disodium 5,5′-bistetrazole-1, 1′-diolate in dimethyl sulfoxide

Hu Niu; Shusen Chen; Shaohua Jin; Lijie Li; Xiaojun Wang; Chunyuan Zhang; Haoming Zou; Qinghai Shu

doi:10.1007/s10973-016-5909-5

Dissolution properties of 5,5′-bistetrazole-1, 1′-dihydroxy and disodium 5,5′-bistetrazole-1, 1′-diolate in dimethyl sulfoxide

Hu Niu, Shusen Chen, Shaohua Jin, Lijie Li, Xiaojun Wang, Chunyuan Zhang, Haoming Zou, Qinghai Shu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The enthalpies of dissolution for 5,5′-Bistetrazole-1, 1′-dihydroxy ((H₂O)₂BTO) and disodium 5,5′-Bistetrazole-1,1′-diolate ([Na₂(H₂O)₄]BTO) in dimethyl sulfoxide (DMSO) at 298.15 K were studied by using a C-80 Calvet microcalorimeter. Empirical formulae for the calculation of the molar enthalpies of dissolution (Δ_dissH), relative partial molar enthalpies (Δ_dissH_partial), and relative apparent molar enthalpies (Δ_dissH_apparent) were deduced by the experimental results of the dissolution processes of (H₂O)₂BTO and [Na₂(H₂O)₄]BTO in DMSO. Finally, the corresponding kinetic equations describing the dissolution processes were dα/dt = 10^−2.60(1−α)^0.61 for the dissolution of (H₂O)₂BTO in DMSO, and dα/dt = 10^−2.69(1−α)^0.62 for the dissolution of [Na₂(H₂O)₄]BTO in DMSO.

Original language	English
Pages (from-to)	615-620
Number of pages	6
Journal	Journal of Thermal Analysis and Calorimetry
Volume	128
Issue number	1
DOIs	https://doi.org/10.1007/s10973-016-5909-5
Publication status	Published - 1 Apr 2017

Keywords

5,5′-bistetrazole-1,1′-dihydroxy
Dimethyl sulfoxide
Disodium 5,5′-bistetrazole-1,1′-diolate
Dissolution
Enthalpies

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title = "Dissolution properties of 5,5′-bistetrazole-1, 1′-dihydroxy and disodium 5,5′-bistetrazole-1, 1′-diolate in dimethyl sulfoxide",

abstract = "The enthalpies of dissolution for 5,5′-Bistetrazole-1, 1′-dihydroxy ((H2O)2BTO) and disodium 5,5′-Bistetrazole-1,1′-diolate ([Na2(H2O)4]BTO) in dimethyl sulfoxide (DMSO) at 298.15 K were studied by using a C-80 Calvet microcalorimeter. Empirical formulae for the calculation of the molar enthalpies of dissolution (ΔdissH), relative partial molar enthalpies (ΔdissHpartial), and relative apparent molar enthalpies (ΔdissHapparent) were deduced by the experimental results of the dissolution processes of (H2O)2BTO and [Na2(H2O)4]BTO in DMSO. Finally, the corresponding kinetic equations describing the dissolution processes were dα/dt = 10−2.60(1−α)0.61 for the dissolution of (H2O)2BTO in DMSO, and dα/dt = 10−2.69(1−α)0.62 for the dissolution of [Na2(H2O)4]BTO in DMSO.",

keywords = "5,5′-bistetrazole-1,1′-dihydroxy, Dimethyl sulfoxide, Disodium 5,5′-bistetrazole-1,1′-diolate, Dissolution, Enthalpies",

author = "Hu Niu and Shusen Chen and Shaohua Jin and Lijie Li and Xiaojun Wang and Chunyuan Zhang and Haoming Zou and Qinghai Shu",

note = "Publisher Copyright: {\textcopyright} 2016, Akad{\'e}miai Kiad{\'o}, Budapest, Hungary.",

year = "2017",

month = apr,

day = "1",

doi = "10.1007/s10973-016-5909-5",

language = "English",

volume = "128",

pages = "615--620",

journal = "Journal of Thermal Analysis and Calorimetry",

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TY - JOUR

T1 - Dissolution properties of 5,5′-bistetrazole-1, 1′-dihydroxy and disodium 5,5′-bistetrazole-1, 1′-diolate in dimethyl sulfoxide

AU - Niu, Hu

AU - Chen, Shusen

AU - Jin, Shaohua

AU - Li, Lijie

AU - Wang, Xiaojun

AU - Zhang, Chunyuan

AU - Zou, Haoming

AU - Shu, Qinghai

PY - 2017/4/1

Y1 - 2017/4/1

N2 - The enthalpies of dissolution for 5,5′-Bistetrazole-1, 1′-dihydroxy ((H2O)2BTO) and disodium 5,5′-Bistetrazole-1,1′-diolate ([Na2(H2O)4]BTO) in dimethyl sulfoxide (DMSO) at 298.15 K were studied by using a C-80 Calvet microcalorimeter. Empirical formulae for the calculation of the molar enthalpies of dissolution (ΔdissH), relative partial molar enthalpies (ΔdissHpartial), and relative apparent molar enthalpies (ΔdissHapparent) were deduced by the experimental results of the dissolution processes of (H2O)2BTO and [Na2(H2O)4]BTO in DMSO. Finally, the corresponding kinetic equations describing the dissolution processes were dα/dt = 10−2.60(1−α)0.61 for the dissolution of (H2O)2BTO in DMSO, and dα/dt = 10−2.69(1−α)0.62 for the dissolution of [Na2(H2O)4]BTO in DMSO.

AB - The enthalpies of dissolution for 5,5′-Bistetrazole-1, 1′-dihydroxy ((H2O)2BTO) and disodium 5,5′-Bistetrazole-1,1′-diolate ([Na2(H2O)4]BTO) in dimethyl sulfoxide (DMSO) at 298.15 K were studied by using a C-80 Calvet microcalorimeter. Empirical formulae for the calculation of the molar enthalpies of dissolution (ΔdissH), relative partial molar enthalpies (ΔdissHpartial), and relative apparent molar enthalpies (ΔdissHapparent) were deduced by the experimental results of the dissolution processes of (H2O)2BTO and [Na2(H2O)4]BTO in DMSO. Finally, the corresponding kinetic equations describing the dissolution processes were dα/dt = 10−2.60(1−α)0.61 for the dissolution of (H2O)2BTO in DMSO, and dα/dt = 10−2.69(1−α)0.62 for the dissolution of [Na2(H2O)4]BTO in DMSO.

KW - 5,5′-bistetrazole-1,1′-dihydroxy

KW - Dimethyl sulfoxide

KW - Disodium 5,5′-bistetrazole-1,1′-diolate

KW - Dissolution

KW - Enthalpies

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U2 - 10.1007/s10973-016-5909-5

DO - 10.1007/s10973-016-5909-5

M3 - Article

AN - SCOPUS:84992702760

SN - 1388-6150

VL - 128

SP - 615

EP - 620

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

IS - 1

ER -

Dissolution properties of 5,5′-bistetrazole-1, 1′-dihydroxy and disodium 5,5′-bistetrazole-1, 1′-diolate in dimethyl sulfoxide

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