Cyclometalated ruthenium(ii) complexes with a bis-carbene CCC-pincer ligand

You Ming Zhang; Jiang Yang Shao; Chang Jiang Yao; Yu Wu Zhong

doi:10.1039/c2dt31015e

Cyclometalated ruthenium(ii) complexes with a bis-carbene CCC-pincer ligand

You Ming Zhang, Jiang Yang Shao, Chang Jiang Yao, Yu Wu Zhong^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4′-di-p-anisylamino-2, 2′:6′,2′′-terpyridine is presented. The Ru ^II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.

Original language	English
Pages (from-to)	9280-9282
Number of pages	3
Journal	Dalton Transactions
Volume	41
Issue number	31
DOIs	https://doi.org/10.1039/c2dt31015e
Publication status	Published - 21 Aug 2012
Externally published	Yes

Access to Document

10.1039/c2dt31015e

Cite this

@article{b4c1d88839574e2e9b80cd44aa0c00c0,

title = "Cyclometalated ruthenium(ii) complexes with a bis-carbene CCC-pincer ligand",

abstract = "The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4′-di-p-anisylamino-2, 2′:6′,2′′-terpyridine is presented. The Ru II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.",

author = "Zhang, {You Ming} and Shao, {Jiang Yang} and Yao, {Chang Jiang} and Zhong, {Yu Wu}",

year = "2012",

month = aug,

day = "21",

doi = "10.1039/c2dt31015e",

language = "English",

volume = "41",

pages = "9280--9282",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "31",

}

TY - JOUR

T1 - Cyclometalated ruthenium(ii) complexes with a bis-carbene CCC-pincer ligand

AU - Zhang, You Ming

AU - Shao, Jiang Yang

AU - Yao, Chang Jiang

AU - Zhong, Yu Wu

PY - 2012/8/21

Y1 - 2012/8/21

N2 - The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4′-di-p-anisylamino-2, 2′:6′,2′′-terpyridine is presented. The Ru II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.

AB - The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4′-di-p-anisylamino-2, 2′:6′,2′′-terpyridine is presented. The Ru II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.

UR - http://www.scopus.com/inward/record.url?scp=84864227819&partnerID=8YFLogxK

U2 - 10.1039/c2dt31015e

DO - 10.1039/c2dt31015e

M3 - Article

AN - SCOPUS:84864227819

SN - 1477-9226

VL - 41

SP - 9280

EP - 9282

JO - Dalton Transactions

JF - Dalton Transactions

IS - 31

ER -

Cyclometalated ruthenium(ii) complexes with a bis-carbene CCC-pincer ligand

Abstract

Access to Document

Other files and links

Fingerprint

Cite this