Cyclometalated ruthenium(ii) complexes with a bis-carbene CCC-pincer ligand

You Ming Zhang; Jiang Yang Shao; Chang Jiang Yao; Yu Wu Zhong

doi:10.1039/c2dt31015e

Cyclometalated ruthenium(ii) complexes with a bis-carbene CCC-pincer ligand

You Ming Zhang, Jiang Yang Shao, Chang Jiang Yao, Yu Wu Zhong^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

43 引用（Scopus）

摘要

The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4′-di-p-anisylamino-2, 2′:6′,2′′-terpyridine is presented. The Ru ^II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.

源语言	英语
页（从-至）	9280-9282
页数	3
期刊	Dalton Transactions
卷	41
期	31
DOI	https://doi.org/10.1039/c2dt31015e
出版状态	已出版 - 21 8月 2012
已对外发布	是

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abstract = "The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4′-di-p-anisylamino-2, 2′:6′,2′′-terpyridine is presented. The Ru II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.",

author = "Zhang, {You Ming} and Shao, {Jiang Yang} and Yao, {Chang Jiang} and Zhong, {Yu Wu}",

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AU - Zhang, You Ming

AU - Shao, Jiang Yang

AU - Yao, Chang Jiang

AU - Zhong, Yu Wu

PY - 2012/8/21

Y1 - 2012/8/21

N2 - The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4′-di-p-anisylamino-2, 2′:6′,2′′-terpyridine is presented. The Ru II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.

AB - The first series of cyclometalated ruthenium complexes with a CCC-pincer bis-carbene ligand have been obtained as bench-stable compounds. Single-crystal X-ray analysis of one of these complexes with 4′-di-p-anisylamino-2, 2′:6′,2′′-terpyridine is presented. The Ru II/III redox potentials and MLCT absorptions of these complexes can be varied by attaching an electron-donating or -withdrawing group on the noncyclometalating ligand.

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Cyclometalated ruthenium(ii) complexes with a bis-carbene CCC-pincer ligand

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