Crystal structures and luminescence properties of a D-A type CIEgen and its Zn(ii) complexes

Jian Biao Song; Gui Lei Liu; Liang Hao; Fang Zhang; Hui Li

doi:10.1039/c9ce00534j

Crystal structures and luminescence properties of a D-A type CIEgen and its Zn(ii) complexes

Jian Biao Song, Gui Lei Liu^*, Liang Hao, Fang Zhang, Hui Li

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A D-A type organic luminogen single crystal (CIE-C) and its two Zn(ii) complexes [Zn(CIE-P)(C₄H₄N₂)·CH₃OH] (1) and [Zn(CIE-P)(4,4′-bipy)·1.5CH₃OH] (2) (CIE-P = 2,3-bis(2,4-dihydroxybenzylideneamino)maleonitrile, C₄H₄N₂ = pyrazine, 4,4′-bipy = 4,4′-bipyridine) have been synthesised and studied. The single crystal X-ray diffraction analysis showed that the molecular structure of CIE-C is well planar and the good co-planarity is maintained in the 2D structure; 1 and 2 are all mononuclear complexes. The photoluminescence properties of CIE-C and its Zn(ii) complexes have been investigated in the solid state and solution. The novel crystallization-induced emission-enhancement (CIEE) behavior of CIE-C and unusual fluorescence selectivity for THF of 1 and 2 were found.

Original language	English
Pages (from-to)	3322-3329
Number of pages	8
Journal	CrystEngComm
Volume	21
Issue number	21
DOIs	https://doi.org/10.1039/c9ce00534j
Publication status	Published - 2019

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@article{a4abb0afe1214ccf931185d24a662c10,

title = "Crystal structures and luminescence properties of a D-A type CIEgen and its Zn(ii) complexes",

abstract = "A D-A type organic luminogen single crystal (CIE-C) and its two Zn(ii) complexes [Zn(CIE-P)(C4H4N2)·CH3OH] (1) and [Zn(CIE-P)(4,4′-bipy)·1.5CH3OH] (2) (CIE-P = 2,3-bis(2,4-dihydroxybenzylideneamino)maleonitrile, C4H4N2 = pyrazine, 4,4′-bipy = 4,4′-bipyridine) have been synthesised and studied. The single crystal X-ray diffraction analysis showed that the molecular structure of CIE-C is well planar and the good co-planarity is maintained in the 2D structure; 1 and 2 are all mononuclear complexes. The photoluminescence properties of CIE-C and its Zn(ii) complexes have been investigated in the solid state and solution. The novel crystallization-induced emission-enhancement (CIEE) behavior of CIE-C and unusual fluorescence selectivity for THF of 1 and 2 were found.",

author = "Song, {Jian Biao} and Liu, {Gui Lei} and Liang Hao and Fang Zhang and Hui Li",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9ce00534j",

language = "English",

volume = "21",

pages = "3322--3329",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "21",

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TY - JOUR

T1 - Crystal structures and luminescence properties of a D-A type CIEgen and its Zn(ii) complexes

AU - Song, Jian Biao

AU - Liu, Gui Lei

AU - Hao, Liang

AU - Zhang, Fang

AU - Li, Hui

PY - 2019

Y1 - 2019

N2 - A D-A type organic luminogen single crystal (CIE-C) and its two Zn(ii) complexes [Zn(CIE-P)(C4H4N2)·CH3OH] (1) and [Zn(CIE-P)(4,4′-bipy)·1.5CH3OH] (2) (CIE-P = 2,3-bis(2,4-dihydroxybenzylideneamino)maleonitrile, C4H4N2 = pyrazine, 4,4′-bipy = 4,4′-bipyridine) have been synthesised and studied. The single crystal X-ray diffraction analysis showed that the molecular structure of CIE-C is well planar and the good co-planarity is maintained in the 2D structure; 1 and 2 are all mononuclear complexes. The photoluminescence properties of CIE-C and its Zn(ii) complexes have been investigated in the solid state and solution. The novel crystallization-induced emission-enhancement (CIEE) behavior of CIE-C and unusual fluorescence selectivity for THF of 1 and 2 were found.

AB - A D-A type organic luminogen single crystal (CIE-C) and its two Zn(ii) complexes [Zn(CIE-P)(C4H4N2)·CH3OH] (1) and [Zn(CIE-P)(4,4′-bipy)·1.5CH3OH] (2) (CIE-P = 2,3-bis(2,4-dihydroxybenzylideneamino)maleonitrile, C4H4N2 = pyrazine, 4,4′-bipy = 4,4′-bipyridine) have been synthesised and studied. The single crystal X-ray diffraction analysis showed that the molecular structure of CIE-C is well planar and the good co-planarity is maintained in the 2D structure; 1 and 2 are all mononuclear complexes. The photoluminescence properties of CIE-C and its Zn(ii) complexes have been investigated in the solid state and solution. The novel crystallization-induced emission-enhancement (CIEE) behavior of CIE-C and unusual fluorescence selectivity for THF of 1 and 2 were found.

UR - http://www.scopus.com/inward/record.url?scp=85066840391&partnerID=8YFLogxK

U2 - 10.1039/c9ce00534j

DO - 10.1039/c9ce00534j

M3 - Article

AN - SCOPUS:85066840391

SN - 1466-8033

VL - 21

SP - 3322

EP - 3329

JO - CrystEngComm

JF - CrystEngComm

IS - 21

ER -

Crystal structures and luminescence properties of a D-A type CIEgen and its Zn(ii) complexes

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