Characteristics of AB3-type co-free hydrogen storage alloy in low-temperature condition

Wei Li, Min Yu Zhang, Dao Bin Mu, Tao Yang, Feng Wu*

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

In this paper, the characteristics of melted and annealed Co-free AB3-type hydrogen storage alloys in low-temperature condition were investigated by electrochemical tests. A series of Co-free AB3-type hydrogen storage alloys were synthesized with vacuum melting method, and be annealed by low-temperature heat treatment. The structures of alloys are simply discussed through SEM and XRD results. And discharge ability and cycle ability of alloys were tested. Experiment results indicate that characteristics of different AB3-type hydrogen storage alloys are affected by low-temperature obviously, and heated treatment could increase the discharge capacity of hydrogen storage alloy effectively, and improve the charge-discharge stability of alloy. Furthermore, non-metal element substituted alloy shows better Low-temperature applicability due to its weak crystallization. The discharge capacity of La0.7Mg0.3Ni2.9B0.05 alloy remains 91.2% after 30 cycles at 273K. And discharge capacity of heated La0.7Mg0.3Ni2.9(FeB)0.1 alloy could reach to 250mA·g-1.

Original languageEnglish
Title of host publicationMaterial and Manufacturing Technology V
PublisherTrans Tech Publications Ltd.
Pages66-70
Number of pages5
ISBN (Print)9783038351498
DOIs
Publication statusPublished - 2014
Event5th International Conference on Material and Manufacturing Technology, ICMMT 2014 - Kuala Lumpur, Malaysia
Duration: 8 May 20149 May 2014

Publication series

NameAdvanced Materials Research
Volume974
ISSN (Print)1022-6680
ISSN (Electronic)1662-8985

Conference

Conference5th International Conference on Material and Manufacturing Technology, ICMMT 2014
Country/TerritoryMalaysia
CityKuala Lumpur
Period8/05/149/05/14

Keywords

  • Low-temperature
  • Substitution

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