Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate

Su Juan Yu; Xiang Yu Gu; Ting Ting Deng; Jian Hao Huang; Jian Wen Cheng; Guo Yu Yang

doi:10.1021/acs.inorgchem.7b02328

Centrosymmetric (Hdima)₂[Ge₅B₃O₁₅(OH)] and Noncentrosymmetric Na₄Ga₃B₄O₁₂(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate

Su Juan Yu, Xiang Yu Gu, Ting Ting Deng, Jian Hao Huang, Jian Wen Cheng^*, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Zhejiang Normal University

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Under solvothermal/surfactant-thermal conditions, two new open-framework borogermanate and galloborate, centrosymmetric (Hdima)₂[Ge₅B₃O₁₅(OH)] (1; dima = dimethylamine) and noncentrosymmetric Na₄Ga₃B₄O₁₂(OH) (2), were obtained and characterized. Compound 1 contains an unusual basket-shaped Ge₅B₃O₁₈(OH) cluster and displays a 3D open-framework layered structure. Compound 2 shows an interrupted 3,4-connected network constructed by alternately linked BO₃ units and Ga³⁺ ions and displays weak second-harmonic-generation response.

Original language	English
Pages (from-to)	12695-12698
Number of pages	4
Journal	Inorganic Chemistry
Volume	56
Issue number	21
DOIs	https://doi.org/10.1021/acs.inorgchem.7b02328
Publication status	Published - 6 Nov 2017

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title = "Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate",

abstract = "Under solvothermal/surfactant-thermal conditions, two new open-framework borogermanate and galloborate, centrosymmetric (Hdima)2[Ge5B3O15(OH)] (1; dima = dimethylamine) and noncentrosymmetric Na4Ga3B4O12(OH) (2), were obtained and characterized. Compound 1 contains an unusual basket-shaped Ge5B3O18(OH) cluster and displays a 3D open-framework layered structure. Compound 2 shows an interrupted 3,4-connected network constructed by alternately linked BO3 units and Ga3+ ions and displays weak second-harmonic-generation response.",

author = "Yu, {Su Juan} and Gu, {Xiang Yu} and Deng, {Ting Ting} and Huang, {Jian Hao} and Cheng, {Jian Wen} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2017",

month = nov,

day = "6",

doi = "10.1021/acs.inorgchem.7b02328",

language = "English",

volume = "56",

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journal = "Inorganic Chemistry",

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TY - JOUR

T1 - Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH)

T2 - Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate

AU - Yu, Su Juan

AU - Gu, Xiang Yu

AU - Deng, Ting Ting

AU - Huang, Jian Hao

AU - Cheng, Jian Wen

AU - Yang, Guo Yu

PY - 2017/11/6

Y1 - 2017/11/6

N2 - Under solvothermal/surfactant-thermal conditions, two new open-framework borogermanate and galloborate, centrosymmetric (Hdima)2[Ge5B3O15(OH)] (1; dima = dimethylamine) and noncentrosymmetric Na4Ga3B4O12(OH) (2), were obtained and characterized. Compound 1 contains an unusual basket-shaped Ge5B3O18(OH) cluster and displays a 3D open-framework layered structure. Compound 2 shows an interrupted 3,4-connected network constructed by alternately linked BO3 units and Ga3+ ions and displays weak second-harmonic-generation response.

AB - Under solvothermal/surfactant-thermal conditions, two new open-framework borogermanate and galloborate, centrosymmetric (Hdima)2[Ge5B3O15(OH)] (1; dima = dimethylamine) and noncentrosymmetric Na4Ga3B4O12(OH) (2), were obtained and characterized. Compound 1 contains an unusual basket-shaped Ge5B3O18(OH) cluster and displays a 3D open-framework layered structure. Compound 2 shows an interrupted 3,4-connected network constructed by alternately linked BO3 units and Ga3+ ions and displays weak second-harmonic-generation response.

UR - http://www.scopus.com/inward/record.url?scp=85033408390&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.7b02328

DO - 10.1021/acs.inorgchem.7b02328

M3 - Article

C2 - 29045136

AN - SCOPUS:85033408390

SN - 0020-1669

VL - 56

SP - 12695

EP - 12698

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

Centrosymmetric (Hdima)₂[Ge₅B₃O₁₅(OH)] and Noncentrosymmetric Na₄Ga₃B₄O₁₂(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate

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