Cd(II) complexes with different nuclearity and dimensionality based on 3-hydrazino-4-amino-1,2,4-triazole

Cai Xia Xu; Jian Guo Zhang; Xin Yin; Xin Jin; Tong Li; Tong Lai Zhang; Zun Ning Zhou

doi:10.1016/j.jssc.2015.02.004

Cd(II) complexes with different nuclearity and dimensionality based on 3-hydrazino-4-amino-1,2,4-triazole

Cai Xia Xu, Jian Guo Zhang^*, Xin Yin, Xin Jin, Tong Li, Tong Lai Zhang, Zun Ning Zhou

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A series of zero- to two-dimensional Cd(II) coordination compounds have been synthesized by the reaction of Cd(II) salts and 3-hydrazino-4-amino-1,2,4-triazole di-hydrochloride (HATr·2HCl). [CdCl₂(HATr)₂] (1) and [Cd₂Cl₄(HATr)₂(H₂O)₂] (2) have discrete mononuclear and binuclear structures, respectively. [Cd(HATr)₂(ClO₄)₂]_n (3) presents polymeric 1-D chain and [Cd₂(NO₃)₂Cl₂(HATr)₂]_n (4) shows 2-D frameworks. All Cd(II) ions exhibit distorted octahedral configurations in 1-3, whilst both hexa and heptacoordinated Cd(II) are formed in 4. The HATr ligands adopt chelating coordinated mode in 1, while tri-dentate bridging-chelating mode in 2-4. The chloride ion is a mono-coordinated ligand in 1 and 2, but it bridges two adjacent metal ions in 4. Furthermore, thermal behaviors have been investigated and the results reveal that all complexes have good thermal stability. The impact sensitivity test indicates that complex 3 is sensitive to impact stimuli.

Original language	English
Pages (from-to)	59-65
Number of pages	7
Journal	Journal of Solid State Chemistry
Volume	226
DOIs	https://doi.org/10.1016/j.jssc.2015.02.004
Publication status	Published - Mar 2015

Keywords

Cd(II)
Crystal structure
Heptacoordinated
Polymeric complexes
Solvothermal method
Thermal analyses

Access to Document

10.1016/j.jssc.2015.02.004

Cite this

@article{bc042bd9b93f40b1abc76e950a94ffd3,

title = "Cd(II) complexes with different nuclearity and dimensionality based on 3-hydrazino-4-amino-1,2,4-triazole",

abstract = "A series of zero- to two-dimensional Cd(II) coordination compounds have been synthesized by the reaction of Cd(II) salts and 3-hydrazino-4-amino-1,2,4-triazole di-hydrochloride (HATr·2HCl). [CdCl2(HATr)2] (1) and [Cd2Cl4(HATr)2(H2O)2] (2) have discrete mononuclear and binuclear structures, respectively. [Cd(HATr)2(ClO4)2]n (3) presents polymeric 1-D chain and [Cd2(NO3)2Cl2(HATr)2]n (4) shows 2-D frameworks. All Cd(II) ions exhibit distorted octahedral configurations in 1-3, whilst both hexa and heptacoordinated Cd(II) are formed in 4. The HATr ligands adopt chelating coordinated mode in 1, while tri-dentate bridging-chelating mode in 2-4. The chloride ion is a mono-coordinated ligand in 1 and 2, but it bridges two adjacent metal ions in 4. Furthermore, thermal behaviors have been investigated and the results reveal that all complexes have good thermal stability. The impact sensitivity test indicates that complex 3 is sensitive to impact stimuli.",

keywords = "Cd(II), Crystal structure, Heptacoordinated, Polymeric complexes, Solvothermal method, Thermal analyses",

author = "Xu, {Cai Xia} and Zhang, {Jian Guo} and Xin Yin and Xin Jin and Tong Li and Zhang, {Tong Lai} and Zhou, {Zun Ning}",

year = "2015",

month = mar,

doi = "10.1016/j.jssc.2015.02.004",

language = "English",

volume = "226",

pages = "59--65",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

}

TY - JOUR

T1 - Cd(II) complexes with different nuclearity and dimensionality based on 3-hydrazino-4-amino-1,2,4-triazole

AU - Xu, Cai Xia

AU - Zhang, Jian Guo

AU - Yin, Xin

AU - Jin, Xin

AU - Li, Tong

AU - Zhang, Tong Lai

AU - Zhou, Zun Ning

PY - 2015/3

Y1 - 2015/3

N2 - A series of zero- to two-dimensional Cd(II) coordination compounds have been synthesized by the reaction of Cd(II) salts and 3-hydrazino-4-amino-1,2,4-triazole di-hydrochloride (HATr·2HCl). [CdCl2(HATr)2] (1) and [Cd2Cl4(HATr)2(H2O)2] (2) have discrete mononuclear and binuclear structures, respectively. [Cd(HATr)2(ClO4)2]n (3) presents polymeric 1-D chain and [Cd2(NO3)2Cl2(HATr)2]n (4) shows 2-D frameworks. All Cd(II) ions exhibit distorted octahedral configurations in 1-3, whilst both hexa and heptacoordinated Cd(II) are formed in 4. The HATr ligands adopt chelating coordinated mode in 1, while tri-dentate bridging-chelating mode in 2-4. The chloride ion is a mono-coordinated ligand in 1 and 2, but it bridges two adjacent metal ions in 4. Furthermore, thermal behaviors have been investigated and the results reveal that all complexes have good thermal stability. The impact sensitivity test indicates that complex 3 is sensitive to impact stimuli.

AB - A series of zero- to two-dimensional Cd(II) coordination compounds have been synthesized by the reaction of Cd(II) salts and 3-hydrazino-4-amino-1,2,4-triazole di-hydrochloride (HATr·2HCl). [CdCl2(HATr)2] (1) and [Cd2Cl4(HATr)2(H2O)2] (2) have discrete mononuclear and binuclear structures, respectively. [Cd(HATr)2(ClO4)2]n (3) presents polymeric 1-D chain and [Cd2(NO3)2Cl2(HATr)2]n (4) shows 2-D frameworks. All Cd(II) ions exhibit distorted octahedral configurations in 1-3, whilst both hexa and heptacoordinated Cd(II) are formed in 4. The HATr ligands adopt chelating coordinated mode in 1, while tri-dentate bridging-chelating mode in 2-4. The chloride ion is a mono-coordinated ligand in 1 and 2, but it bridges two adjacent metal ions in 4. Furthermore, thermal behaviors have been investigated and the results reveal that all complexes have good thermal stability. The impact sensitivity test indicates that complex 3 is sensitive to impact stimuli.

KW - Cd(II)

KW - Crystal structure

KW - Heptacoordinated

KW - Polymeric complexes

KW - Solvothermal method

KW - Thermal analyses

UR - http://www.scopus.com/inward/record.url?scp=84923380109&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2015.02.004

DO - 10.1016/j.jssc.2015.02.004

M3 - Article

AN - SCOPUS:84923380109

SN - 0022-4596

VL - 226

SP - 59

EP - 65

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -

Cd(II) complexes with different nuclearity and dimensionality based on 3-hydrazino-4-amino-1,2,4-triazole

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this