TY - JOUR
T1 - Assembly of an A6L6 Anion Trigonal Antiprism and Binding of Glucopyranosides and Polyethylene Glycols (PEGs)
AU - Li, Boyang
AU - Wei, Tianfu
AU - Zhao, Xiaotong
AU - Wang, Yue
AU - Xu, Lizheng
AU - Yang, Xiao Juan
AU - Wu, Biao
N1 - Publisher Copyright:
© 2023 Wiley-VCH GmbH.
PY - 2023/5/8
Y1 - 2023/5/8
N2 - Anion-coordination-driven assembly (ACDA) has proven to be a very effective strategy for the construction of polyhedral structures. Here we demonstrate that variation of the “angle” of the backbone of C3-symmetric tris-bis(urea) ligands, from triphenylamine to triphenylphosphine oxide, results in the change of the final construct from an A4L4 tetrahedron to a higher-nuclearity, A6L6 trigonal antiprism (A=anion, herein PO43−; L=ligand). Most interestingly, this assembly features a huge hollow internal space that is divided into three compartments: one central cavity and two large outer pockets. This multi-cavity character enables the binding of different guests, namely monosaccharides or polyethylene glycol molecules (PEG600, PEG1000 and PEG2000), respectively. The results prove that anion coordination by multiple hydrogen bonds may provide both sufficient strength and flexibility, thus making possible the formation of complicated structures with adaptive guest binding ability.
AB - Anion-coordination-driven assembly (ACDA) has proven to be a very effective strategy for the construction of polyhedral structures. Here we demonstrate that variation of the “angle” of the backbone of C3-symmetric tris-bis(urea) ligands, from triphenylamine to triphenylphosphine oxide, results in the change of the final construct from an A4L4 tetrahedron to a higher-nuclearity, A6L6 trigonal antiprism (A=anion, herein PO43−; L=ligand). Most interestingly, this assembly features a huge hollow internal space that is divided into three compartments: one central cavity and two large outer pockets. This multi-cavity character enables the binding of different guests, namely monosaccharides or polyethylene glycol molecules (PEG600, PEG1000 and PEG2000), respectively. The results prove that anion coordination by multiple hydrogen bonds may provide both sufficient strength and flexibility, thus making possible the formation of complicated structures with adaptive guest binding ability.
KW - Anion-Coordination-Driven Assembly (ACDA)
KW - Glucopyranosides
KW - Host-Guest Chemistry
KW - Polyethylene Glycols
KW - Trigonal Antiprisms
UR - http://www.scopus.com/inward/record.url?scp=85151407828&partnerID=8YFLogxK
U2 - 10.1002/anie.202301300
DO - 10.1002/anie.202301300
M3 - Article
C2 - 36892527
AN - SCOPUS:85151407828
SN - 1433-7851
VL - 62
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 20
M1 - e202301300
ER -