An unprecedented example of a heterotrimetallic main-group [L 2Al2Ge4Li2S7] cluster containing a GeII-GeII donor-acceptor bond

Zhi Yang; Xiaoli Ma; Rainer B. Oswald; Herbert W. Roesky; Chunming Cui; Hans Georg Schmidt; Mathias Noltemeyer

doi:10.1002/anie.200503940

An unprecedented example of a heterotrimetallic main-group [L ₂Al₂Ge₄Li₂S₇] cluster containing a Ge^II-Ge^II donor-acceptor bond

Zhi Yang^*, Xiaoli Ma, Rainer B. Oswald, Herbert W. Roesky, Chunming Cui, Hans Georg Schmidt, Mathias Noltemeyer

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

(Chemical Equation Presented) Donations accepted : The reaction of [{LAl[(SLi)₂(thf)₂]}₂] (L = HC(CMeNAr) ₂, Ar = 2,6-iPr₂C₆H₃) with GeCl ₂·dioxane yields the novel Ge^II→Ge ^II-containing hetero-trimetallic [L₂Al₂Ge ₄Li₂S₇] cluster, which has a crablike structure (Al gray, Ge magenta, Li orange, S yellow, O green, N blue, C light gray). This cluster is the first aluminum-containing hetero-trimetallic sulfide.

Original language	English
Pages (from-to)	2277-2280
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	14
DOIs	https://doi.org/10.1002/anie.200503940
Publication status	Published - 27 Mar 2006
Externally published	Yes

Keywords

Aluminum
Cluster compounds
Germanium
N ligands
Sulfur

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10.1002/anie.200503940

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title = "An unprecedented example of a heterotrimetallic main-group [L 2Al2Ge4Li2S7] cluster containing a GeII-GeII donor-acceptor bond",

abstract = "(Chemical Equation Presented) Donations accepted : The reaction of [{LAl[(SLi)2(thf)2]}2] (L = HC(CMeNAr) 2, Ar = 2,6-iPr2C6H3) with GeCl 2·dioxane yields the novel GeII→Ge II-containing hetero-trimetallic [L2Al2Ge 4Li2S7] cluster, which has a crablike structure (Al gray, Ge magenta, Li orange, S yellow, O green, N blue, C light gray). This cluster is the first aluminum-containing hetero-trimetallic sulfide.",

keywords = "Aluminum, Cluster compounds, Germanium, N ligands, Sulfur",

author = "Zhi Yang and Xiaoli Ma and Oswald, {Rainer B.} and Roesky, {Herbert W.} and Chunming Cui and Schmidt, {Hans Georg} and Mathias Noltemeyer",

year = "2006",

month = mar,

day = "27",

doi = "10.1002/anie.200503940",

language = "English",

volume = "45",

pages = "2277--2280",

journal = "Angewandte Chemie - International Edition",

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T1 - An unprecedented example of a heterotrimetallic main-group [L 2Al2Ge4Li2S7] cluster containing a GeII-GeII donor-acceptor bond

AU - Yang, Zhi

AU - Ma, Xiaoli

AU - Oswald, Rainer B.

AU - Roesky, Herbert W.

AU - Cui, Chunming

AU - Schmidt, Hans Georg

AU - Noltemeyer, Mathias

PY - 2006/3/27

Y1 - 2006/3/27

N2 - (Chemical Equation Presented) Donations accepted : The reaction of [{LAl[(SLi)2(thf)2]}2] (L = HC(CMeNAr) 2, Ar = 2,6-iPr2C6H3) with GeCl 2·dioxane yields the novel GeII→Ge II-containing hetero-trimetallic [L2Al2Ge 4Li2S7] cluster, which has a crablike structure (Al gray, Ge magenta, Li orange, S yellow, O green, N blue, C light gray). This cluster is the first aluminum-containing hetero-trimetallic sulfide.

AB - (Chemical Equation Presented) Donations accepted : The reaction of [{LAl[(SLi)2(thf)2]}2] (L = HC(CMeNAr) 2, Ar = 2,6-iPr2C6H3) with GeCl 2·dioxane yields the novel GeII→Ge II-containing hetero-trimetallic [L2Al2Ge 4Li2S7] cluster, which has a crablike structure (Al gray, Ge magenta, Li orange, S yellow, O green, N blue, C light gray). This cluster is the first aluminum-containing hetero-trimetallic sulfide.

KW - Aluminum

KW - Cluster compounds

KW - Germanium

KW - N ligands

KW - Sulfur

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DO - 10.1002/anie.200503940

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VL - 45

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JO - Angewandte Chemie - International Edition

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An unprecedented example of a heterotrimetallic main-group [L ₂Al₂Ge₄Li₂S₇] cluster containing a Ge^II-Ge^II donor-acceptor bond

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Keywords

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