A novel ternary energetic compound: DAF/DNP/H2O cocrystal

Xiaopeng Zhang; Yige Wu; Shaohua Jin; Guanchao Lan; Xiaojun Wang; Junfeng Wang; Fenqing Shang; Shusen Chen; Junyi Du; Qinghai Shu

doi:10.1080/07370652.2022.2028035

A novel ternary energetic compound: DAF/DNP/H₂O cocrystal

Xiaopeng Zhang, Yige Wu, Shaohua Jin, Guanchao Lan, Xiaojun Wang, Junfeng Wang, Fenqing Shang, Shusen Chen, Junyi Du^*, Qinghai Shu

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A novel ternary energetic cocrystal composed of 3,4-diaminofurazan (DAF), 3,4-dinitropyrazole (DNP), and H₂O in a 1:1:1 stoichiometry with low impact sensitivity is reported. This cocrystal has a predicted detonation velocity higher than DAF and TNT. Preliminary attempts are reported to obtain the even more energetic cocrystals DAF/DNP and DAF/DNP/H₂O₂. For the latter, an original approach based on the urea/H₂O₂ cocrystal as a source of H₂O₂ is described.

Original language	English
Pages (from-to)	84-96
Number of pages	13
Journal	Journal of Energetic Materials
Volume	42
Issue number	1
DOIs	https://doi.org/10.1080/07370652.2022.2028035
Publication status	Published - 2024

Keywords

Cocrystal
energetic material
sensitivity
ternary

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10.1080/07370652.2022.2028035

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title = "A novel ternary energetic compound: DAF/DNP/H2O cocrystal",

abstract = "A novel ternary energetic cocrystal composed of 3,4-diaminofurazan (DAF), 3,4-dinitropyrazole (DNP), and H2O in a 1:1:1 stoichiometry with low impact sensitivity is reported. This cocrystal has a predicted detonation velocity higher than DAF and TNT. Preliminary attempts are reported to obtain the even more energetic cocrystals DAF/DNP and DAF/DNP/H2O2. For the latter, an original approach based on the urea/H2O2 cocrystal as a source of H2O2 is described.",

keywords = "Cocrystal, energetic material, sensitivity, ternary",

author = "Xiaopeng Zhang and Yige Wu and Shaohua Jin and Guanchao Lan and Xiaojun Wang and Junfeng Wang and Fenqing Shang and Shusen Chen and Junyi Du and Qinghai Shu",

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year = "2024",

doi = "10.1080/07370652.2022.2028035",

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T1 - A novel ternary energetic compound

T2 - DAF/DNP/H2O cocrystal

AU - Zhang, Xiaopeng

AU - Wu, Yige

AU - Jin, Shaohua

AU - Lan, Guanchao

AU - Wang, Xiaojun

AU - Wang, Junfeng

AU - Shang, Fenqing

AU - Chen, Shusen

AU - Du, Junyi

AU - Shu, Qinghai

PY - 2024

Y1 - 2024

N2 - A novel ternary energetic cocrystal composed of 3,4-diaminofurazan (DAF), 3,4-dinitropyrazole (DNP), and H2O in a 1:1:1 stoichiometry with low impact sensitivity is reported. This cocrystal has a predicted detonation velocity higher than DAF and TNT. Preliminary attempts are reported to obtain the even more energetic cocrystals DAF/DNP and DAF/DNP/H2O2. For the latter, an original approach based on the urea/H2O2 cocrystal as a source of H2O2 is described.

AB - A novel ternary energetic cocrystal composed of 3,4-diaminofurazan (DAF), 3,4-dinitropyrazole (DNP), and H2O in a 1:1:1 stoichiometry with low impact sensitivity is reported. This cocrystal has a predicted detonation velocity higher than DAF and TNT. Preliminary attempts are reported to obtain the even more energetic cocrystals DAF/DNP and DAF/DNP/H2O2. For the latter, an original approach based on the urea/H2O2 cocrystal as a source of H2O2 is described.

KW - Cocrystal

KW - energetic material

KW - sensitivity

KW - ternary

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DO - 10.1080/07370652.2022.2028035

M3 - Article

AN - SCOPUS:85123318490

SN - 0737-0652

VL - 42

SP - 84

EP - 96

JO - Journal of Energetic Materials

JF - Journal of Energetic Materials

IS - 1

ER -

A novel ternary energetic compound: DAF/DNP/H₂O cocrystal

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Keywords

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