A novel supramolecular magnesoborate framework with snowflake-like channels built by unprecedented huge B69 cluster cages

Jia Jia Wang; Guo Yu Yang

doi:10.1039/c7cc05404a

A novel supramolecular magnesoborate framework with snowflake-like channels built by unprecedented huge B₆₉ cluster cages

Jia Jia Wang, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

A novel magnesoborate, Mg₇at[B₆₉O₁₀₈(OH)₁₈], with a 3D supramolecular framework has been made under solvothermal conditions, and features wonderful snowflake-like channels assembled from unprecedented [B₆₉O₁₀₈(OH)₁₈] clusters. Notably, unique triple-helical ribbons reside in the middle of the B₆₉ cluster. Up to now, the discovery of a B₆₉ cluster sets a new record in cluster sizes among borates.

Original language	English
Pages (from-to)	10398-10401
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	75
DOIs	https://doi.org/10.1039/c7cc05404a
Publication status	Published - 2017

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abstract = "A novel magnesoborate, Mg7at[B69O108(OH)18], with a 3D supramolecular framework has been made under solvothermal conditions, and features wonderful snowflake-like channels assembled from unprecedented [B69O108(OH)18] clusters. Notably, unique triple-helical ribbons reside in the middle of the B69 cluster. Up to now, the discovery of a B69 cluster sets a new record in cluster sizes among borates.",

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AB - A novel magnesoborate, Mg7at[B69O108(OH)18], with a 3D supramolecular framework has been made under solvothermal conditions, and features wonderful snowflake-like channels assembled from unprecedented [B69O108(OH)18] clusters. Notably, unique triple-helical ribbons reside in the middle of the B69 cluster. Up to now, the discovery of a B69 cluster sets a new record in cluster sizes among borates.

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A novel supramolecular magnesoborate framework with snowflake-like channels built by unprecedented huge B₆₉ cluster cages

Abstract

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