A novel 3D metal-organic framework with helical structure: Synthesis and structure of [Ag4(tzdt)4(μ-tzdtH)2]n (tzdtH=1,3-thiazolidine-2-thione)

Xian Yin Wei; Wei Chu; Ru Dan Huang; Shao Wen Zhang; Hui Li; Qin Lei Zhu

doi:10.1016/j.inoche.2006.07.021

A novel 3D metal-organic framework with helical structure: Synthesis and structure of [Ag₄(tzdt)₄(μ-tzdtH)₂]_n (tzdtH=1,3-thiazolidine-2-thione)

Xian Yin Wei, Wei Chu, Ru Dan Huang^*, Shao Wen Zhang, Hui Li, Qin Lei Zhu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A novel metal-organic framework (MOF), the first 3D 1,3-thiazolidine-2-thione (tzdtH) coordinated MOF with strong Ag-Ag interaction (2.9001 Å) in tetranuclear silver clusters, was synthesized. The single-crystal X-ray diffraction shows that the versatile ligand tzdtH contributes greatly to the formation of the 3D framework and the helical structure.

Original language	English
Pages (from-to)	1161-1164
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	9
Issue number	12
DOIs	https://doi.org/10.1016/j.inoche.2006.07.021
Publication status	Published - Dec 2006

Keywords

1,3-Thiazolidine-2-thione
Helical structure
Single-crystal X-ray diffraction
Strong Ag-Ag interaction

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10.1016/j.inoche.2006.07.021

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title = "A novel 3D metal-organic framework with helical structure: Synthesis and structure of [Ag4(tzdt)4(μ-tzdtH)2]n (tzdtH=1,3-thiazolidine-2-thione)",

abstract = "A novel metal-organic framework (MOF), the first 3D 1,3-thiazolidine-2-thione (tzdtH) coordinated MOF with strong Ag-Ag interaction (2.9001 {\AA}) in tetranuclear silver clusters, was synthesized. The single-crystal X-ray diffraction shows that the versatile ligand tzdtH contributes greatly to the formation of the 3D framework and the helical structure.",

keywords = "1,3-Thiazolidine-2-thione, Helical structure, Single-crystal X-ray diffraction, Strong Ag-Ag interaction",

author = "Wei, {Xian Yin} and Wei Chu and Huang, {Ru Dan} and Zhang, {Shao Wen} and Hui Li and Zhu, {Qin Lei}",

year = "2006",

month = dec,

doi = "10.1016/j.inoche.2006.07.021",

language = "English",

volume = "9",

pages = "1161--1164",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - A novel 3D metal-organic framework with helical structure

T2 - Synthesis and structure of [Ag4(tzdt)4(μ-tzdtH)2]n (tzdtH=1,3-thiazolidine-2-thione)

AU - Wei, Xian Yin

AU - Chu, Wei

AU - Huang, Ru Dan

AU - Zhang, Shao Wen

AU - Li, Hui

AU - Zhu, Qin Lei

PY - 2006/12

Y1 - 2006/12

N2 - A novel metal-organic framework (MOF), the first 3D 1,3-thiazolidine-2-thione (tzdtH) coordinated MOF with strong Ag-Ag interaction (2.9001 Å) in tetranuclear silver clusters, was synthesized. The single-crystal X-ray diffraction shows that the versatile ligand tzdtH contributes greatly to the formation of the 3D framework and the helical structure.

AB - A novel metal-organic framework (MOF), the first 3D 1,3-thiazolidine-2-thione (tzdtH) coordinated MOF with strong Ag-Ag interaction (2.9001 Å) in tetranuclear silver clusters, was synthesized. The single-crystal X-ray diffraction shows that the versatile ligand tzdtH contributes greatly to the formation of the 3D framework and the helical structure.

KW - 1,3-Thiazolidine-2-thione

KW - Helical structure

KW - Single-crystal X-ray diffraction

KW - Strong Ag-Ag interaction

UR - http://www.scopus.com/inward/record.url?scp=33751034847&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2006.07.021

DO - 10.1016/j.inoche.2006.07.021

M3 - Article

AN - SCOPUS:33751034847

SN - 1387-7003

VL - 9

SP - 1161

EP - 1164

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 12

ER -

A novel 3D metal-organic framework with helical structure: Synthesis and structure of [Ag₄(tzdt)₄(μ-tzdtH)₂]_n (tzdtH=1,3-thiazolidine-2-thione)

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Keywords

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