A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF)

Min Jie Wu; Shu Sen Chen; Shao Hua Jin; Li Jie Li

doi:10.3969/j.issn.1006-9941.2013.02.024

A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF)

Min Jie Wu^*, Shu Sen Chen, Shao Hua Jin, Li Jie Li

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF) which used 3, 4-diaminofurazan as raw material and 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan as intermediate was introduced. 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan was oxygenating by 30% H₂O₂ in solvent of 1, 4-dioxane. After refluxing for 4 h, DAOAF was obtainded with yield 97% or 89%. The product was characterized by ¹H NMR, ¹³C NMR, IR and EI.

Original language	English
Pages (from-to)	273-275
Number of pages	3
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	21
Issue number	2
DOIs	https://doi.org/10.3969/j.issn.1006-9941.2013.02.024
Publication status	Published - Apr 2013

Keywords

3'-diamino-4, 4'-azoxyfurazan
3, 4-diaminofurazan
3-amino-4-formylaminofurazan
Organic chemistry
Synthesis

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10.3969/j.issn.1006-9941.2013.02.024

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title = "A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF)",

abstract = "A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF) which used 3, 4-diaminofurazan as raw material and 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan as intermediate was introduced. 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan was oxygenating by 30% H2O2 in solvent of 1, 4-dioxane. After refluxing for 4 h, DAOAF was obtainded with yield 97% or 89%. The product was characterized by 1H NMR, 13C NMR, IR and EI.",

keywords = "3'-diamino-4, 4'-azoxyfurazan, 3, 4-diaminofurazan, 3-amino-4-formylaminofurazan, Organic chemistry, Synthesis",

author = "Wu, {Min Jie} and Chen, {Shu Sen} and Jin, {Shao Hua} and Li, {Li Jie}",

year = "2013",

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doi = "10.3969/j.issn.1006-9941.2013.02.024",

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AU - Chen, Shu Sen

AU - Jin, Shao Hua

AU - Li, Li Jie

PY - 2013/4

Y1 - 2013/4

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AB - A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF) which used 3, 4-diaminofurazan as raw material and 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan as intermediate was introduced. 3-amino-4-formylaminofurazan or 3, 4-diformylaminofurazan was oxygenating by 30% H2O2 in solvent of 1, 4-dioxane. After refluxing for 4 h, DAOAF was obtainded with yield 97% or 89%. The product was characterized by 1H NMR, 13C NMR, IR and EI.

KW - 3'-diamino-4, 4'-azoxyfurazan

KW - 3, 4-diaminofurazan

KW - 3-amino-4-formylaminofurazan

KW - Organic chemistry

KW - Synthesis

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A new method to synthesize 3, 3'-diamino-4, 4'-azoxyfurazan (DAOAF)

Abstract

Keywords

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