A New diiminopyridyl cobalt complex [C0CI2L] (L = 2,6-Bis(N,Ń-bis(2,6-diisopropyl-4-(2, 3-dimethyoxylbenzoylamide) phenylimino))pyridine)

Ze Rong Long; Qi Long Zhao; Shao Guang Li; Ya Na Xia; Biao Wu

A New diiminopyridyl cobalt complex [C0CI₂L] (L = 2,6-Bis(N,Ń-bis(2,6-diisopropyl-4-(2, 3-dimethyoxylbenzoylamide) phenylimino))pyridine)

Ze Rong Long, Qi Long Zhao, Shao Guang Li, Ya Na Xia, Biao Wu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of CoCl₂ 6H₂O with 2,6-bis(N,Ń- bis(2,6-diisopropyl-4-(2,3-dimethy- oxyl-benzoylamide)phenylimino))pyridine (L) afforded the complex [CoCl₂L], which was fully characterized by elemental analysis, UV-vis, IR spectroscopy, fluorescence, and X-ray diffraction analysis. The compound is of triclinic system, space group P1̄ with a = 13.058(3), b = 13.798(3), c = 16.695(3) Å, α = 98.191(3), β = 102.792(3), γ = 101.820(3)°, V = 2815.0(9) Å³, Z = 2, F(000) = 1122, μ = 0.45 mm^-1, R = 0.061 and wR = 0.1349 for 9842 observed reflections (I > 2σ{I)). The Co(II) center adopts a distorted square-pyramidal coordination geometry. The extended structure shows a one-dimensional zigzag double chain linked by hydrogen bonds and π-π stacking interactions.

Original language	English
Pages (from-to)	869-874
Number of pages	6
Journal	Jiegou Huaxue
Volume	29
Issue number	6
Publication status	Published - 2010
Externally published	Yes

Keywords

2,6-bis(N,Ń
Bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide) phenylimino)) pyridine
Cobalt
Crystal structure
Fluorescence

Cite this

@article{2cdabdff4bd14345a86b9d52a2975088,

title = "A New diiminopyridyl cobalt complex [C0CI2L] (L = 2,6-Bis(N,{\'N}-bis(2,6-diisopropyl-4-(2, 3-dimethyoxylbenzoylamide) phenylimino))pyridine)",

abstract = "The reaction of CoCl2 6H2O with 2,6-bis(N,{\'N}- bis(2,6-diisopropyl-4-(2,3-dimethy- oxyl-benzoylamide)phenylimino))pyridine (L) afforded the complex [CoCl2L], which was fully characterized by elemental analysis, UV-vis, IR spectroscopy, fluorescence, and X-ray diffraction analysis. The compound is of triclinic system, space group P{\=1} with a = 13.058(3), b = 13.798(3), c = 16.695(3) {\AA}, α = 98.191(3), β = 102.792(3), γ = 101.820(3)°, V = 2815.0(9) {\AA}3, Z = 2, F(000) = 1122, μ = 0.45 mm-1, R = 0.061 and wR = 0.1349 for 9842 observed reflections (I > 2σ{I)). The Co(II) center adopts a distorted square-pyramidal coordination geometry. The extended structure shows a one-dimensional zigzag double chain linked by hydrogen bonds and π-π stacking interactions.",

keywords = "2,6-bis(N,{\'N}, Bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide) phenylimino)) pyridine, Cobalt, Crystal structure, Fluorescence",

author = "Long, {Ze Rong} and Zhao, {Qi Long} and Li, {Shao Guang} and Xia, {Ya Na} and Biao Wu",

year = "2010",

language = "English",

volume = "29",

pages = "869--874",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "6",

}

TY - JOUR

T1 - A New diiminopyridyl cobalt complex [C0CI2L] (L = 2,6-Bis(N,Ń-bis(2,6-diisopropyl-4-(2, 3-dimethyoxylbenzoylamide) phenylimino))pyridine)

AU - Long, Ze Rong

AU - Zhao, Qi Long

AU - Li, Shao Guang

AU - Xia, Ya Na

AU - Wu, Biao

PY - 2010

Y1 - 2010

N2 - The reaction of CoCl2 6H2O with 2,6-bis(N,Ń- bis(2,6-diisopropyl-4-(2,3-dimethy- oxyl-benzoylamide)phenylimino))pyridine (L) afforded the complex [CoCl2L], which was fully characterized by elemental analysis, UV-vis, IR spectroscopy, fluorescence, and X-ray diffraction analysis. The compound is of triclinic system, space group P1̄ with a = 13.058(3), b = 13.798(3), c = 16.695(3) Å, α = 98.191(3), β = 102.792(3), γ = 101.820(3)°, V = 2815.0(9) Å3, Z = 2, F(000) = 1122, μ = 0.45 mm-1, R = 0.061 and wR = 0.1349 for 9842 observed reflections (I > 2σ{I)). The Co(II) center adopts a distorted square-pyramidal coordination geometry. The extended structure shows a one-dimensional zigzag double chain linked by hydrogen bonds and π-π stacking interactions.

AB - The reaction of CoCl2 6H2O with 2,6-bis(N,Ń- bis(2,6-diisopropyl-4-(2,3-dimethy- oxyl-benzoylamide)phenylimino))pyridine (L) afforded the complex [CoCl2L], which was fully characterized by elemental analysis, UV-vis, IR spectroscopy, fluorescence, and X-ray diffraction analysis. The compound is of triclinic system, space group P1̄ with a = 13.058(3), b = 13.798(3), c = 16.695(3) Å, α = 98.191(3), β = 102.792(3), γ = 101.820(3)°, V = 2815.0(9) Å3, Z = 2, F(000) = 1122, μ = 0.45 mm-1, R = 0.061 and wR = 0.1349 for 9842 observed reflections (I > 2σ{I)). The Co(II) center adopts a distorted square-pyramidal coordination geometry. The extended structure shows a one-dimensional zigzag double chain linked by hydrogen bonds and π-π stacking interactions.

KW - 2,6-bis(N,Ń

KW - Bis(2,6-diisopropyl-4-(2,3-dimethyoxylbenzoylamide) phenylimino)) pyridine

KW - Cobalt

KW - Crystal structure

KW - Fluorescence

UR - http://www.scopus.com/inward/record.url?scp=77953827433&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:77953827433

SN - 0254-5861

VL - 29

SP - 869

EP - 874

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 6

ER -

A New diiminopyridyl cobalt complex [C0CI₂L] (L = 2,6-Bis(N,Ń-bis(2,6-diisopropyl-4-(2, 3-dimethyoxylbenzoylamide) phenylimino))pyridine)

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