A New 2-D Inorganic–Organic Hybrid Polyoxometalate Based on Mono-Cu-Substituted [CuSiW11O39]n        6n− Chains and [Cu(en)2]2+ Bridges

Peng Chao Ci; Zhong Zhang; Bai Feng Yang; Xin Xiong Li; Guo Yu Yang

doi:10.1007/s10876-016-1138-0

A New 2-D Inorganic–Organic Hybrid Polyoxometalate Based on Mono-Cu-Substituted [CuSiW₁₁O₃₉]_n ⁶ⁿ⁻ Chains and [Cu(en)₂]²⁺ Bridges

Peng Chao Ci, Zhong Zhang, Bai Feng Yang, Xin Xiong Li, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Abstract: A new organic–inorganic hybrid polyoxometalate H₂[Cu(en)₂(H₂O)]₂[Cu(en)₂]{[Cu(en)₂]₃ (CuSiW₁₁O₃₉)₂}·6H₂O (1) (en = ethylenediamine) have been hydrothermally synthesized and characterized by IR spectrum, thermogravimetric analysis, power X-ray diffraction and single-crystal X-ray diffraction. Crystal data for 1: monoclinic, P2₁/c, a = 18.8077(3) Å, b = 23.0703(5) Å, c = 26.0723(6) Å, β = 96.438(2)°, Z = 4. Single-crystal X-ray diffraction analysis revealed that 1 exhibits a 2-dimensional network constructed from mono-Cu-substituted [CuSiW₁₁O₃₉]_n ⁶ⁿ⁻ chains and [Cu(en)₂]²⁺ bridges. Graphical Abstract: A new organic–inorganic hybrid polyoxometalate H₂[Cu(en)₂(H₂O)]₂[Cu(en)₂]{[Cu(en)₂]₃(CuSiW₁₁O₃₉)₂}·6H₂O (1) (en = ethylenediamine) have been hydrothermally synthesized and characterized, which exhibits a 2-dimensional network constructed from mono-Cu-substituted [CuSiW₁₁O₃₉]_n ⁶ⁿ⁻ chains and [Cu(en)₂]²⁺ bridges.[Figure not available: see fulltext.]

Original language	English
Pages (from-to)	1249-1257
Number of pages	9
Journal	Journal of Cluster Science
Volume	28
Issue number	3
DOIs	https://doi.org/10.1007/s10876-016-1138-0
Publication status	Published - 1 May 2017

Keywords

Copper
Crystal structure
Hydrothermal synthesis
Organic–inorganic hybrid
Polyoxometalates

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10.1007/s10876-016-1138-0

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@article{4b49da79439d40cb8e71688322534b8e,

title = "A New 2-D Inorganic–Organic Hybrid Polyoxometalate Based on Mono-Cu-Substituted [CuSiW11O39]n 6n− Chains and [Cu(en)2]2+ Bridges",

abstract = "Abstract: A new organic–inorganic hybrid polyoxometalate H2[Cu(en)2(H2O)]2[Cu(en)2]{[Cu(en)2]3 (CuSiW11O39)2}·6H2O (1) (en = ethylenediamine) have been hydrothermally synthesized and characterized by IR spectrum, thermogravimetric analysis, power X-ray diffraction and single-crystal X-ray diffraction. Crystal data for 1: monoclinic, P21/c, a = 18.8077(3) {\AA}, b = 23.0703(5) {\AA}, c = 26.0723(6) {\AA}, β = 96.438(2)°, Z = 4. Single-crystal X-ray diffraction analysis revealed that 1 exhibits a 2-dimensional network constructed from mono-Cu-substituted [CuSiW11O39]n 6n− chains and [Cu(en)2]2+ bridges. Graphical Abstract: A new organic–inorganic hybrid polyoxometalate H2[Cu(en)2(H2O)]2[Cu(en)2]{[Cu(en)2]3(CuSiW11O39)2}·6H2O (1) (en = ethylenediamine) have been hydrothermally synthesized and characterized, which exhibits a 2-dimensional network constructed from mono-Cu-substituted [CuSiW11O39]n 6n− chains and [Cu(en)2]2+ bridges.[Figure not available: see fulltext.]",

keywords = "Copper, Crystal structure, Hydrothermal synthesis, Organic–inorganic hybrid, Polyoxometalates",

author = "Ci, {Peng Chao} and Zhong Zhang and Yang, {Bai Feng} and Li, {Xin Xiong} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2016, Springer Science+Business Media New York.",

year = "2017",

month = may,

day = "1",

doi = "10.1007/s10876-016-1138-0",

language = "English",

volume = "28",

pages = "1249--1257",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "3",

}

TY - JOUR

T1 - A New 2-D Inorganic–Organic Hybrid Polyoxometalate Based on Mono-Cu-Substituted [CuSiW11O39]n 6n− Chains and [Cu(en)2]2+ Bridges

AU - Ci, Peng Chao

AU - Zhang, Zhong

AU - Yang, Bai Feng

AU - Li, Xin Xiong

AU - Yang, Guo Yu

PY - 2017/5/1

Y1 - 2017/5/1

N2 - Abstract: A new organic–inorganic hybrid polyoxometalate H2[Cu(en)2(H2O)]2[Cu(en)2]{[Cu(en)2]3 (CuSiW11O39)2}·6H2O (1) (en = ethylenediamine) have been hydrothermally synthesized and characterized by IR spectrum, thermogravimetric analysis, power X-ray diffraction and single-crystal X-ray diffraction. Crystal data for 1: monoclinic, P21/c, a = 18.8077(3) Å, b = 23.0703(5) Å, c = 26.0723(6) Å, β = 96.438(2)°, Z = 4. Single-crystal X-ray diffraction analysis revealed that 1 exhibits a 2-dimensional network constructed from mono-Cu-substituted [CuSiW11O39]n 6n− chains and [Cu(en)2]2+ bridges. Graphical Abstract: A new organic–inorganic hybrid polyoxometalate H2[Cu(en)2(H2O)]2[Cu(en)2]{[Cu(en)2]3(CuSiW11O39)2}·6H2O (1) (en = ethylenediamine) have been hydrothermally synthesized and characterized, which exhibits a 2-dimensional network constructed from mono-Cu-substituted [CuSiW11O39]n 6n− chains and [Cu(en)2]2+ bridges.[Figure not available: see fulltext.]

AB - Abstract: A new organic–inorganic hybrid polyoxometalate H2[Cu(en)2(H2O)]2[Cu(en)2]{[Cu(en)2]3 (CuSiW11O39)2}·6H2O (1) (en = ethylenediamine) have been hydrothermally synthesized and characterized by IR spectrum, thermogravimetric analysis, power X-ray diffraction and single-crystal X-ray diffraction. Crystal data for 1: monoclinic, P21/c, a = 18.8077(3) Å, b = 23.0703(5) Å, c = 26.0723(6) Å, β = 96.438(2)°, Z = 4. Single-crystal X-ray diffraction analysis revealed that 1 exhibits a 2-dimensional network constructed from mono-Cu-substituted [CuSiW11O39]n 6n− chains and [Cu(en)2]2+ bridges. Graphical Abstract: A new organic–inorganic hybrid polyoxometalate H2[Cu(en)2(H2O)]2[Cu(en)2]{[Cu(en)2]3(CuSiW11O39)2}·6H2O (1) (en = ethylenediamine) have been hydrothermally synthesized and characterized, which exhibits a 2-dimensional network constructed from mono-Cu-substituted [CuSiW11O39]n 6n− chains and [Cu(en)2]2+ bridges.[Figure not available: see fulltext.]

KW - Copper

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Organic–inorganic hybrid

KW - Polyoxometalates

UR - http://www.scopus.com/inward/record.url?scp=85006427094&partnerID=8YFLogxK

U2 - 10.1007/s10876-016-1138-0

DO - 10.1007/s10876-016-1138-0

M3 - Article

AN - SCOPUS:85006427094

SN - 1040-7278

VL - 28

SP - 1249

EP - 1257

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 3

ER -

A New 2-D Inorganic–Organic Hybrid Polyoxometalate Based on Mono-Cu-Substituted [CuSiW₁₁O₃₉]_n ⁶ⁿ⁻ Chains and [Cu(en)₂]²⁺ Bridges

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