A multi-fused heat-resistant energetic compound constructed by hydrogen bonds

Yong Hu; Wen Shuai Dong; Zu Jia Lu; Han Zhang; Jian Guo Zhang

doi:10.1039/d3cc02504g

A multi-fused heat-resistant energetic compound constructed by hydrogen bonds

Yong Hu, Wen Shuai Dong, Zu Jia Lu, Han Zhang, Jian Guo Zhang^*

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The design of heat-resistant energetic compounds generally employs symmetry, planarity, and multi-hydrogen bonds to obtain compounds with high density, good thermal stability, and low sensitivity. In this paper, a heat-resistant hydrazine-bridged compound, 6,6′-(hydrazine-1,2-diyl)bis(5-nitropyrimidine-2,4-diamine) (PHP), was designed and synthesized with the strategy of multi-fused conjugated structure constructed by hydrogen bonds. The compound featured high symmetry, high planarity, and strong conjugation with good thermal stability (364 °C). This strategy provides a basis for the design of heat-resistant energetic compounds.

Original language	English
Pages (from-to)	9864-9867
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	65
DOIs	https://doi.org/10.1039/d3cc02504g
Publication status	Published - 13 Jul 2023

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Hu, Y., Dong, W. S., Lu, Z. J., Zhang, H., & Zhang, J. G. (2023). A multi-fused heat-resistant energetic compound constructed by hydrogen bonds. Chemical Communications, 59(65), 9864-9867. https://doi.org/10.1039/d3cc02504g

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abstract = "The design of heat-resistant energetic compounds generally employs symmetry, planarity, and multi-hydrogen bonds to obtain compounds with high density, good thermal stability, and low sensitivity. In this paper, a heat-resistant hydrazine-bridged compound, 6,6′-(hydrazine-1,2-diyl)bis(5-nitropyrimidine-2,4-diamine) (PHP), was designed and synthesized with the strategy of multi-fused conjugated structure constructed by hydrogen bonds. The compound featured high symmetry, high planarity, and strong conjugation with good thermal stability (364 °C). This strategy provides a basis for the design of heat-resistant energetic compounds.",

author = "Yong Hu and Dong, {Wen Shuai} and Lu, {Zu Jia} and Han Zhang and Zhang, {Jian Guo}",

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AU - Zhang, Jian Guo

PY - 2023/7/13

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AB - The design of heat-resistant energetic compounds generally employs symmetry, planarity, and multi-hydrogen bonds to obtain compounds with high density, good thermal stability, and low sensitivity. In this paper, a heat-resistant hydrazine-bridged compound, 6,6′-(hydrazine-1,2-diyl)bis(5-nitropyrimidine-2,4-diamine) (PHP), was designed and synthesized with the strategy of multi-fused conjugated structure constructed by hydrogen bonds. The compound featured high symmetry, high planarity, and strong conjugation with good thermal stability (364 °C). This strategy provides a basis for the design of heat-resistant energetic compounds.

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A multi-fused heat-resistant energetic compound constructed by hydrogen bonds

Abstract

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