A hydrogen-bonded tubular structure of zinc(ii) and methyl-3- pyridylcarbamate

Ya Na Xia; Shao Guang Li; Ze Rong Long; Biao Wu

A hydrogen-bonded tubular structure of zinc(ii) and methyl-3- pyridylcarbamate

Ya Na Xia, Shao Guang Li, Ze Rong Long, Biao Wu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A zinc(II) compound [ZnCl₂(mpcm)₂] (1, mpcm = methyl-3-pyridylcarbamate) was prepared by solvothermal reaction and characterized by elemental analysis, IR spectroscopy, TGA and single-crystal X-ray diffraction. The crystal is of monoclinic system, space group p2 ₁/n, C₁₄H₁₆ZnCl₂N₄O ₄, M_r = 440.58, a = 8.7893(7), b = 24.978(2), c = 9.2510(8) Å, β = 109.318(1)°, V= 1916.6(3) A°³, Z = 4, θ = 1.63∼25.20°, D_c = 1.527 g/cm³, μ = 1.585 mm^-1, F(000) = 896, the final R = 0.0255 and wR = 0.0654 for 3080 observed reflections with I > 2σ(I). The zinc atom is four-coordinated by the pyridyl groups of two mpcm ligands and two chloride ions with a tetrahedral geometry. Two [ZnCl₂(mpcm)₂] subunits are held together by a pair of hydrogen bonds, forming a 32-membered macrocyclic dimer, which is further extended into a 3D tubular structure via hydrogen bonding.

Original language	English
Pages (from-to)	875-878
Number of pages	4
Journal	Jiegou Huaxue
Volume	29
Issue number	6
Publication status	Published - 2010
Externally published	Yes

Keywords

Hydrogen-bonded tubular structure
Methyl-3-pyridylcarbamate
Zinc

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title = "A hydrogen-bonded tubular structure of zinc(ii) and methyl-3- pyridylcarbamate",

abstract = "A zinc(II) compound [ZnCl2(mpcm)2] (1, mpcm = methyl-3-pyridylcarbamate) was prepared by solvothermal reaction and characterized by elemental analysis, IR spectroscopy, TGA and single-crystal X-ray diffraction. The crystal is of monoclinic system, space group p2 1/n, C14H16ZnCl2N4O 4, Mr = 440.58, a = 8.7893(7), b = 24.978(2), c = 9.2510(8) {\AA}, β = 109.318(1)°, V= 1916.6(3) A°3, Z = 4, θ = 1.63∼25.20°, Dc = 1.527 g/cm3, μ = 1.585 mm-1, F(000) = 896, the final R = 0.0255 and wR = 0.0654 for 3080 observed reflections with I > 2σ(I). The zinc atom is four-coordinated by the pyridyl groups of two mpcm ligands and two chloride ions with a tetrahedral geometry. Two [ZnCl2(mpcm)2] subunits are held together by a pair of hydrogen bonds, forming a 32-membered macrocyclic dimer, which is further extended into a 3D tubular structure via hydrogen bonding.",

keywords = "Hydrogen-bonded tubular structure, Methyl-3-pyridylcarbamate, Zinc",

author = "Xia, {Ya Na} and Li, {Shao Guang} and Long, {Ze Rong} and Biao Wu",

year = "2010",

language = "English",

volume = "29",

pages = "875--878",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "6",

}

TY - JOUR

T1 - A hydrogen-bonded tubular structure of zinc(ii) and methyl-3- pyridylcarbamate

AU - Xia, Ya Na

AU - Li, Shao Guang

AU - Long, Ze Rong

AU - Wu, Biao

PY - 2010

Y1 - 2010

N2 - A zinc(II) compound [ZnCl2(mpcm)2] (1, mpcm = methyl-3-pyridylcarbamate) was prepared by solvothermal reaction and characterized by elemental analysis, IR spectroscopy, TGA and single-crystal X-ray diffraction. The crystal is of monoclinic system, space group p2 1/n, C14H16ZnCl2N4O 4, Mr = 440.58, a = 8.7893(7), b = 24.978(2), c = 9.2510(8) Å, β = 109.318(1)°, V= 1916.6(3) A°3, Z = 4, θ = 1.63∼25.20°, Dc = 1.527 g/cm3, μ = 1.585 mm-1, F(000) = 896, the final R = 0.0255 and wR = 0.0654 for 3080 observed reflections with I > 2σ(I). The zinc atom is four-coordinated by the pyridyl groups of two mpcm ligands and two chloride ions with a tetrahedral geometry. Two [ZnCl2(mpcm)2] subunits are held together by a pair of hydrogen bonds, forming a 32-membered macrocyclic dimer, which is further extended into a 3D tubular structure via hydrogen bonding.

AB - A zinc(II) compound [ZnCl2(mpcm)2] (1, mpcm = methyl-3-pyridylcarbamate) was prepared by solvothermal reaction and characterized by elemental analysis, IR spectroscopy, TGA and single-crystal X-ray diffraction. The crystal is of monoclinic system, space group p2 1/n, C14H16ZnCl2N4O 4, Mr = 440.58, a = 8.7893(7), b = 24.978(2), c = 9.2510(8) Å, β = 109.318(1)°, V= 1916.6(3) A°3, Z = 4, θ = 1.63∼25.20°, Dc = 1.527 g/cm3, μ = 1.585 mm-1, F(000) = 896, the final R = 0.0255 and wR = 0.0654 for 3080 observed reflections with I > 2σ(I). The zinc atom is four-coordinated by the pyridyl groups of two mpcm ligands and two chloride ions with a tetrahedral geometry. Two [ZnCl2(mpcm)2] subunits are held together by a pair of hydrogen bonds, forming a 32-membered macrocyclic dimer, which is further extended into a 3D tubular structure via hydrogen bonding.

KW - Hydrogen-bonded tubular structure

KW - Methyl-3-pyridylcarbamate

KW - Zinc

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M3 - Article

AN - SCOPUS:77953840570

SN - 0254-5861

VL - 29

SP - 875

EP - 878

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 6

ER -

A hydrogen-bonded tubular structure of zinc(ii) and methyl-3- pyridylcarbamate

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