1D Structure Sodium Coordination Anion based on [5-(Dinitromethylene)-4,5-dihydro-1H-tetrazole]: Syntheses, Structures, and Thermal Behavior

Le Wu; Jian Guo Zhang; Jin Ting Wu; Xin Yin; Piao He

doi:10.1002/zaac.201600171

1D Structure Sodium Coordination Anion based on [5-(Dinitromethylene)-4,5-dihydro-1H-tetrazole]: Syntheses, Structures, and Thermal Behavior

Le Wu, Jian Guo Zhang^*, Jin Ting Wu, Xin Yin, Piao He

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The ten-coordinate complex, (HATr)[Na(DNMz)]·H₂O (1) was synthesized by reaction of 5-(dinitromethylene)-4,5-dihydro-1H-tetrazole (DNMz), sodium hydroxide, and 3-hydrazinium-4-amino-1,2,4-1H-triazolium dichloride (HATr) in aqueous solution and characterized by various physico-chemical techniques. Complex 1 is an energetic material with a nitrogen content of 51.2 % and a decomposition temperature of 128.9 °C. The molecular structure of complex 1 crystallizes in the monoclinic system with P2(1)/c group and shows an infinite 1D chain structure. The heat of formation was determined as –122.27 kJ·mol^–1by using bomb calorimetry. In addition, the kinetic parameters were studied by Kissinger's and Ozawa-Doyle's methods.

Original language	English
Pages (from-to)	949-952
Number of pages	4
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	642
Issue number	18
DOIs	https://doi.org/10.1002/zaac.201600171
Publication status	Published - Sept 2016

Keywords

5-(Dinitromethylene)-4,5-dihydro-1H-tetrazole
Crystal structure
Nitrogen-rich
Sodium coordination anion
Thermal behavior

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title = "1D Structure Sodium Coordination Anion based on [5-(Dinitromethylene)-4,5-dihydro-1H-tetrazole]: Syntheses, Structures, and Thermal Behavior",

abstract = "The ten-coordinate complex, (HATr)[Na(DNMz)]·H2O (1) was synthesized by reaction of 5-(dinitromethylene)-4,5-dihydro-1H-tetrazole (DNMz), sodium hydroxide, and 3-hydrazinium-4-amino-1,2,4-1H-triazolium dichloride (HATr) in aqueous solution and characterized by various physico-chemical techniques. Complex 1 is an energetic material with a nitrogen content of 51.2 % and a decomposition temperature of 128.9 °C. The molecular structure of complex 1 crystallizes in the monoclinic system with P2(1)/c group and shows an infinite 1D chain structure. The heat of formation was determined as –122.27 kJ·mol–1by using bomb calorimetry. In addition, the kinetic parameters were studied by Kissinger's and Ozawa-Doyle's methods.",

keywords = "5-(Dinitromethylene)-4,5-dihydro-1H-tetrazole, Crystal structure, Nitrogen-rich, Sodium coordination anion, Thermal behavior",

author = "Le Wu and Zhang, {Jian Guo} and Wu, {Jin Ting} and Xin Yin and Piao He",

note = "Publisher Copyright: Copyright {\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2016",

month = sep,

doi = "10.1002/zaac.201600171",

language = "English",

volume = "642",

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TY - JOUR

T1 - 1D Structure Sodium Coordination Anion based on [5-(Dinitromethylene)-4,5-dihydro-1H-tetrazole]

T2 - Syntheses, Structures, and Thermal Behavior

AU - Wu, Le

AU - Zhang, Jian Guo

AU - Wu, Jin Ting

AU - Yin, Xin

AU - He, Piao

PY - 2016/9

Y1 - 2016/9

N2 - The ten-coordinate complex, (HATr)[Na(DNMz)]·H2O (1) was synthesized by reaction of 5-(dinitromethylene)-4,5-dihydro-1H-tetrazole (DNMz), sodium hydroxide, and 3-hydrazinium-4-amino-1,2,4-1H-triazolium dichloride (HATr) in aqueous solution and characterized by various physico-chemical techniques. Complex 1 is an energetic material with a nitrogen content of 51.2 % and a decomposition temperature of 128.9 °C. The molecular structure of complex 1 crystallizes in the monoclinic system with P2(1)/c group and shows an infinite 1D chain structure. The heat of formation was determined as –122.27 kJ·mol–1by using bomb calorimetry. In addition, the kinetic parameters were studied by Kissinger's and Ozawa-Doyle's methods.

AB - The ten-coordinate complex, (HATr)[Na(DNMz)]·H2O (1) was synthesized by reaction of 5-(dinitromethylene)-4,5-dihydro-1H-tetrazole (DNMz), sodium hydroxide, and 3-hydrazinium-4-amino-1,2,4-1H-triazolium dichloride (HATr) in aqueous solution and characterized by various physico-chemical techniques. Complex 1 is an energetic material with a nitrogen content of 51.2 % and a decomposition temperature of 128.9 °C. The molecular structure of complex 1 crystallizes in the monoclinic system with P2(1)/c group and shows an infinite 1D chain structure. The heat of formation was determined as –122.27 kJ·mol–1by using bomb calorimetry. In addition, the kinetic parameters were studied by Kissinger's and Ozawa-Doyle's methods.

KW - 5-(Dinitromethylene)-4,5-dihydro-1H-tetrazole

KW - Crystal structure

KW - Nitrogen-rich

KW - Sodium coordination anion

KW - Thermal behavior

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U2 - 10.1002/zaac.201600171

DO - 10.1002/zaac.201600171

M3 - Article

AN - SCOPUS:84981712807

SN - 0044-2313

VL - 642

SP - 949

EP - 952

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 18

ER -

1D Structure Sodium Coordination Anion based on [5-(Dinitromethylene)-4,5-dihydro-1H-tetrazole]: Syntheses, Structures, and Thermal Behavior

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Keywords

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