Two discrete cu-complexes constructed from a multidentate N-containing dinucleating ligand

Yan Qing Xu; Pei Lei Xia; Yuan Zhe Gao; Ling Ren; Chang Wen Hu

Two discrete cu-complexes constructed from a multidentate N-containing dinucleating ligand

Yan Qing Xu^*, Pei Lei Xia, Yuan Zhe Gao, Ling Ren, Chang Wen Hu

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

Two comparable discrete complexes [Cu^II(CH₃CN) ₂L₂]·2(ClO₄) 1 and [Cu¹ ₂I₂L₂]· (DMF)₂ 2 were successfully synthesized by the reaction of Cu^II and Cu^I salts with a novel dinucleating ligand 2,5-bis(3-pyridinylmethylthio)-l,3,4- thiadiazole) (L), respectively. Complex 1 presents a single nuclear structure while 2 has a dimeric structure where two Cu^I ions are doubly bridged by halide ions in a μ₂-fashion. Both discrete molecules were outspreaded into a one-dimensional supramolecular chain via aromatic interactions such as C-H⋯π and π-π interactions.

源语言	英语
页（从-至）	459-464
页数	6
期刊	Jiegou Huaxue
卷	29
期	3
出版状态	已出版 - 2010

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title = "Two discrete cu-complexes constructed from a multidentate N-containing dinucleating ligand",

abstract = "Two comparable discrete complexes [CuII(CH3CN) 2L2]·2(ClO4) 1 and [Cu1 2I2L2]· (DMF)2 2 were successfully synthesized by the reaction of CuII and CuI salts with a novel dinucleating ligand 2,5-bis(3-pyridinylmethylthio)-l,3,4- thiadiazole) (L), respectively. Complex 1 presents a single nuclear structure while 2 has a dimeric structure where two CuI ions are doubly bridged by halide ions in a μ2-fashion. Both discrete molecules were outspreaded into a one-dimensional supramolecular chain via aromatic interactions such as C-H⋯π and π-π interactions.",

keywords = "Aromatic interactions, Chelating coordination, Flexible ligand, Thiadiazole group",

author = "Xu, {Yan Qing} and Xia, {Pei Lei} and Gao, {Yuan Zhe} and Ling Ren and Hu, {Chang Wen}",

year = "2010",

language = "English",

volume = "29",

pages = "459--464",

journal = "Jiegou Huaxue",

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T1 - Two discrete cu-complexes constructed from a multidentate N-containing dinucleating ligand

AU - Xu, Yan Qing

AU - Xia, Pei Lei

AU - Gao, Yuan Zhe

AU - Ren, Ling

AU - Hu, Chang Wen

PY - 2010

Y1 - 2010

N2 - Two comparable discrete complexes [CuII(CH3CN) 2L2]·2(ClO4) 1 and [Cu1 2I2L2]· (DMF)2 2 were successfully synthesized by the reaction of CuII and CuI salts with a novel dinucleating ligand 2,5-bis(3-pyridinylmethylthio)-l,3,4- thiadiazole) (L), respectively. Complex 1 presents a single nuclear structure while 2 has a dimeric structure where two CuI ions are doubly bridged by halide ions in a μ2-fashion. Both discrete molecules were outspreaded into a one-dimensional supramolecular chain via aromatic interactions such as C-H⋯π and π-π interactions.

AB - Two comparable discrete complexes [CuII(CH3CN) 2L2]·2(ClO4) 1 and [Cu1 2I2L2]· (DMF)2 2 were successfully synthesized by the reaction of CuII and CuI salts with a novel dinucleating ligand 2,5-bis(3-pyridinylmethylthio)-l,3,4- thiadiazole) (L), respectively. Complex 1 presents a single nuclear structure while 2 has a dimeric structure where two CuI ions are doubly bridged by halide ions in a μ2-fashion. Both discrete molecules were outspreaded into a one-dimensional supramolecular chain via aromatic interactions such as C-H⋯π and π-π interactions.

KW - Aromatic interactions

KW - Chelating coordination

KW - Flexible ligand

KW - Thiadiazole group

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AN - SCOPUS:77951235678

SN - 0254-5861

VL - 29

SP - 459

EP - 464

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 3

ER -

Two discrete cu-complexes constructed from a multidentate N-containing dinucleating ligand

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