Theoretical study on the isomerization mechanism of enol ester from 2-acyl-1, 3-cyclohexanediones

Yan Hua Wang*, Jian Wei Zou, Bing Zhang, Min Zeng, Gui Xiang Hu, Ke Wen Zheng, Qing Sen Yu

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

3 引用 (Scopus)

摘要

The present paper employed density function theory to investigate two reaction pathways for isomerization of enol ester proposed by Yang(path a) and the present authors(path a), respectively. The base catalytic effects of solvent triethylamine on these two reactions were also evaluated. It is demonstrated that path B is more preferable than path a due to low barrier height for the rate-determining step.

源语言英语
页(从-至)705-708
页数4
期刊Chinese Chemical Letters
16
5
出版状态已出版 - 5月 2005
已对外发布

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