The preparation and structure determination of perchlorate tricarbohydrazide manganese (II)

Tonglai Zhang; Jianguo Zhang; Zhigang Zhang; Zhaorong Wei; Kaibei Yu

The preparation and structure determination of perchlorate tricarbohydrazide manganese (II)

Tonglai Zhang^*, Jianguo Zhang, Zhigang Zhang, Zhaorong Wei, Kaibei Yu

^*此作品的通讯作者

机电学院

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

A new coordination compound was prepared by mixing aqueous solution of carbohydrazide and manganese perchlorate. It was also characterized by elemental analysis, IR and DSC analysis. The molecular and crystal structure of perchlorate tricarbohydrazide Manganese (II) was determined by X-ray crystallography. (The crystalline is monoclinic with space group P2 ₁/n. The coordination compound could be expressed in the formula of [Mn(CHZ)₃](C1O₄)₂ with crystal parameters: a = 1.0197(2)nm, b = 0.8593(1)nm, c = 2.1412(3)nm, β = 100.86, V = 1.8426(5)nm³, Z = 4. The results suggest that all carbohydrazide molecules coordinated with central ion as bidentates through oxygen atom of carbonyl group and one terminal nitrogen atom, and linked with Manganese to form three five-number rings.

源语言	英语
页（从-至）	13-19
页数	7
期刊	Chemical Journal on Internet
卷	2
期	5
出版状态	已出版 - 14 5月 2000

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@article{a6e63e100f9b4a89933faf914ed9aca9,

title = "The preparation and structure determination of perchlorate tricarbohydrazide manganese (II)",

abstract = "A new coordination compound was prepared by mixing aqueous solution of carbohydrazide and manganese perchlorate. It was also characterized by elemental analysis, IR and DSC analysis. The molecular and crystal structure of perchlorate tricarbohydrazide Manganese (II) was determined by X-ray crystallography. (The crystalline is monoclinic with space group P2 1/n. The coordination compound could be expressed in the formula of [Mn(CHZ)3](C1O4)2 with crystal parameters: a = 1.0197(2)nm, b = 0.8593(1)nm, c = 2.1412(3)nm, β = 100.86, V = 1.8426(5)nm3, Z = 4. The results suggest that all carbohydrazide molecules coordinated with central ion as bidentates through oxygen atom of carbonyl group and one terminal nitrogen atom, and linked with Manganese to form three five-number rings.",

keywords = "Carbohydrazide, Crystal structure, Manganese perchlorate, Molecular structure, Preparation",

author = "Tonglai Zhang and Jianguo Zhang and Zhigang Zhang and Zhaorong Wei and Kaibei Yu",

year = "2000",

month = may,

day = "14",

language = "English",

volume = "2",

pages = "13--19",

journal = "Chemical Journal on Internet",

issn = "1523-1623",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "5",

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TY - JOUR

T1 - The preparation and structure determination of perchlorate tricarbohydrazide manganese (II)

AU - Zhang, Tonglai

AU - Zhang, Jianguo

AU - Zhang, Zhigang

AU - Wei, Zhaorong

AU - Yu, Kaibei

PY - 2000/5/14

Y1 - 2000/5/14

N2 - A new coordination compound was prepared by mixing aqueous solution of carbohydrazide and manganese perchlorate. It was also characterized by elemental analysis, IR and DSC analysis. The molecular and crystal structure of perchlorate tricarbohydrazide Manganese (II) was determined by X-ray crystallography. (The crystalline is monoclinic with space group P2 1/n. The coordination compound could be expressed in the formula of [Mn(CHZ)3](C1O4)2 with crystal parameters: a = 1.0197(2)nm, b = 0.8593(1)nm, c = 2.1412(3)nm, β = 100.86, V = 1.8426(5)nm3, Z = 4. The results suggest that all carbohydrazide molecules coordinated with central ion as bidentates through oxygen atom of carbonyl group and one terminal nitrogen atom, and linked with Manganese to form three five-number rings.

AB - A new coordination compound was prepared by mixing aqueous solution of carbohydrazide and manganese perchlorate. It was also characterized by elemental analysis, IR and DSC analysis. The molecular and crystal structure of perchlorate tricarbohydrazide Manganese (II) was determined by X-ray crystallography. (The crystalline is monoclinic with space group P2 1/n. The coordination compound could be expressed in the formula of [Mn(CHZ)3](C1O4)2 with crystal parameters: a = 1.0197(2)nm, b = 0.8593(1)nm, c = 2.1412(3)nm, β = 100.86, V = 1.8426(5)nm3, Z = 4. The results suggest that all carbohydrazide molecules coordinated with central ion as bidentates through oxygen atom of carbonyl group and one terminal nitrogen atom, and linked with Manganese to form three five-number rings.

KW - Carbohydrazide

KW - Crystal structure

KW - Manganese perchlorate

KW - Molecular structure

KW - Preparation

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M3 - Article

AN - SCOPUS:3242733082

SN - 1523-1623

VL - 2

SP - 13

EP - 19

JO - Chemical Journal on Internet

JF - Chemical Journal on Internet

IS - 5

ER -

The preparation and structure determination of perchlorate tricarbohydrazide manganese (II)

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