Tetrahedral anion cage: Self-assembly of a (PO4) 4L4 complex from a tris(bisurea) ligand

Biao Wu, Fengjuan Cui, Yibo Lei, Shaoguang Li, Nader De Sousa Amadeu, Christoph Janiak, Yue Jian Lin, Lin Hong Weng, Yao Yu Wang, Xiao Juan Yang

科研成果: 期刊稿件文章同行评审

78 引用 (Scopus)

摘要

A C3-symmetric tris(bisurea) ligand L assembles with PO 43- ions to form the tetrahedral cage [(PO 4)4L4]12-. The PO4 3- ions form the four vertices and each forms 12 N-H⋯O hydrogen bonds with 6 urea groups. A unique trinuclear pinwheel-like helical complex [(SO4)3L2]6- is formed from L and SO42- ions (see picture).

源语言英语
页(从-至)5096-5100
页数5
期刊Angewandte Chemie - International Edition
52
19
DOI
出版状态已出版 - 3 5月 2013
已对外发布

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