Synthesis, structure and phase transition of a new microporous aluminophosphate [C4N2H14]2+ [H2Al3 P3O14]2-

Hui Ying Lu, Xiao Qiang Tong, Yan Yan, Wen Fu Yan*, Ji Hong Yu, Ru Ren Xu

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

11 引用 (Scopus)

摘要

In the presence of N-methyl-1, 3-diaminopropane, a new microporous aluminophosphate compound [C4N2H14]2+ [H2Al3P3 O14]2-(1) was synthesized under hydrothermal condition. Single-crystal X-ray diffraction structural analysis showed that compound 1 crystallizes in the orthorhombic space group Pbca with a=1.59839(11) nm, b=0.99402(6) nm, c=1.82261(11) nm, V=2.8958(3) nm3. Its framework consists of AlO5/AlO6 and PO4 units forming 10-ring channels along [010] direction, where the templates exists. Compound 1 transformed to AlPO4-25(ATV) upon calcination at 550 °C. It was further characterized by powder X-ray diffraction(PXRD), inductively coupled plasma(ICP) analysis, scanning electron microscopy(SEM), thermal gravimetric(TG) analysis, and elemental analysis.

源语言英语
页(从-至)1571-1575
页数5
期刊Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
34
7
DOI
出版状态已出版 - 7月 2013
已对外发布

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Lu, H. Y., Tong, X. Q., Yan, Y., Yan, W. F., Yu, J. H., & Xu, R. R. (2013). Synthesis, structure and phase transition of a new microporous aluminophosphate [C4N2H14]2+ [H2Al3 P3O14]2-. Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 34(7), 1571-1575. https://doi.org/10.7503/cjcu20130245