Synthesis of water soluble polyrotaxanes by end-capping polypseudo-rotaxanes of γ-CDs with PHEMA-PPO-PEO-PPO-PHEMA using ATRP of MPC

Tao Kong; Jing Lin; Lin Ye; Ai Ying Zhang; Zeng Guo Feng

doi:10.1039/c5py00674k

Synthesis of water soluble polyrotaxanes by end-capping polypseudo-rotaxanes of γ-CDs with PHEMA-PPO-PEO-PPO-PHEMA using ATRP of MPC

Tao Kong, Jing Lin, Lin Ye, Ai Ying Zhang, Zeng Guo Feng^*

^*此作品的通讯作者

材料学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

17 引用（Scopus）

摘要

A twice ATRP protocol is developed for the preparation of water soluble single-chain stranded polyrotaxanes (PRs) by end-capping polypseudorotaxanes (PPRs) formed from γ-CDs with PHEMA-PPO-PEO-PPO-PHEMA using oligomers of MPC as a bulky stopper. It is shown that those threaded γ-CDs simultaneously reside on PHEMA and PEG segments to give access to both loose- and over-fit structured PR-based multi-block copolymers.

源语言	英语
页（从-至）	5832-5837
页数	6
期刊	Polymer Chemistry
卷	6
期	32
DOI	https://doi.org/10.1039/c5py00674k
出版状态	已出版 - 28 8月 2015

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Kong, T., Lin, J., Ye, L., Zhang, A. Y., & Feng, Z. G. (2015). Synthesis of water soluble polyrotaxanes by end-capping polypseudo-rotaxanes of γ-CDs with PHEMA-PPO-PEO-PPO-PHEMA using ATRP of MPC. Polymer Chemistry, 6(32), 5832-5837. https://doi.org/10.1039/c5py00674k

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abstract = "A twice ATRP protocol is developed for the preparation of water soluble single-chain stranded polyrotaxanes (PRs) by end-capping polypseudorotaxanes (PPRs) formed from γ-CDs with PHEMA-PPO-PEO-PPO-PHEMA using oligomers of MPC as a bulky stopper. It is shown that those threaded γ-CDs simultaneously reside on PHEMA and PEG segments to give access to both loose- and over-fit structured PR-based multi-block copolymers.",

author = "Tao Kong and Jing Lin and Lin Ye and Zhang, {Ai Ying} and Feng, {Zeng Guo}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2015",

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doi = "10.1039/c5py00674k",

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AU - Lin, Jing

AU - Ye, Lin

AU - Zhang, Ai Ying

AU - Feng, Zeng Guo

PY - 2015/8/28

Y1 - 2015/8/28

N2 - A twice ATRP protocol is developed for the preparation of water soluble single-chain stranded polyrotaxanes (PRs) by end-capping polypseudorotaxanes (PPRs) formed from γ-CDs with PHEMA-PPO-PEO-PPO-PHEMA using oligomers of MPC as a bulky stopper. It is shown that those threaded γ-CDs simultaneously reside on PHEMA and PEG segments to give access to both loose- and over-fit structured PR-based multi-block copolymers.

AB - A twice ATRP protocol is developed for the preparation of water soluble single-chain stranded polyrotaxanes (PRs) by end-capping polypseudorotaxanes (PPRs) formed from γ-CDs with PHEMA-PPO-PEO-PPO-PHEMA using oligomers of MPC as a bulky stopper. It is shown that those threaded γ-CDs simultaneously reside on PHEMA and PEG segments to give access to both loose- and over-fit structured PR-based multi-block copolymers.

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Synthesis of water soluble polyrotaxanes by end-capping polypseudo-rotaxanes of γ-CDs with PHEMA-PPO-PEO-PPO-PHEMA using ATRP of MPC

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