摘要
4,4',6,6'-Tetra(azido) azo-1,3,5-triazine(TAAT) was synthesized with cyanuric chloride and hydrazine hydrate as primary materials. This synthesis is a four-step process including coupling, hydrazinolysis, diazotization and oxidation in turn. Each reaction process, especially the oxidizing reaction is described in details. The investigation indicates that chlorine can transform 94% 4,4',6,6'-tetra(azido)hydrazo-1,3,5-triazine into TAAT but N-bromosuccinimide just transforms 84%. The DSC, IR, NMR and elemental analysis determine the structure of TAAT and its intermediates. The characterization of DSC shows TAAT decomposes at 198°C. A free radical mechanism is presented to interpret the oxidizing reaction.
| 源语言 | 英语 |
|---|---|
| 页（从-至） | 485-489 |
| 页数 | 5 |
| 期刊 | Hanneng Cailiao/Chinese Journal of Energetic Materials |
| 卷 | 15 |
| 期 | 5 |
| 出版状态 | 已出版 - 10月 2007 |
指纹
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Li, X. T., Pang, S. P., Yu, Y. Z., & Luo, Y. J. (2007). Synthesis of high-nitrogen compound of 4,4',6,6'-tetra(azido) azo-1,3,5-triazine. Hanneng Cailiao/Chinese Journal of Energetic Materials, 15(5), 485-489.