Synthesis, characterization and thermal stability of the aluminum boroxine-linked compound with N-aryl substituted β-Diketiminato Ligand

Peng Fei Hao, Zhi Yang*, Xiao Li Ma, Jia Rong Li

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

6 引用 (Scopus)

摘要

The reaction of LA1H2 (L=(Z)-4-[(2,6-diisopropylphenyl)amino]pent-3-en-2-ylidene-2,6-diisopropylaniline) with 2-trifluoromethylphenylboronic acid resulted in the boroxine-linked organic aluminum compound LAI [OB(2-CF3C6H4)]2 (μ-O). Compound is an unique example of a spiro-centered aluminum atom, showing the inorganic A1O3B2 ring fused to the organic C3N2 part. Compound was characterized by 1H NMR, IR, elemental analysis, and single crystal X-ray structural analysis. Furthermore, compound was studied by TG analysis.

源语言英语
页(从-至)1909-1913
页数5
期刊Chinese Journal of Inorganic Chemistry
29
9
DOI
出版状态已出版 - 9月 2013

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Hao, P. F., Yang, Z., Ma, X. L., & Li, J. R. (2013). Synthesis, characterization and thermal stability of the aluminum boroxine-linked compound with N-aryl substituted β-Diketiminato Ligand. Chinese Journal of Inorganic Chemistry, 29(9), 1909-1913. https://doi.org/10.3969/j.issn.1001-4861.2013.00.296