Synthesis and Structure of a Tetracapped Keggin Polyarsenomolybdovanadate [Co(en)3][Co(en)2(H2O)2]2 • [MoV4MoVI4VIV 8O40(AsO4)] Containing Different Coordinated Cations

Qing Xin Zeng; Ji Qing Xu; Guo Yu Yang; Ya Feng Li; Xiao Bing Cui; Xiao Li Zhao; Chuan Bi Li

Synthesis and Structure of a Tetracapped Keggin Polyarsenomolybdovanadate [Co(en)₃][Co(en)₂(H₂O)₂]₂ • [Mo^V₄Mo^VI₄V^IV ₈O₄₀(AsO₄)] Containing Different Coordinated Cations

Qing Xin Zeng, Ji Qing Xu^*, Guo Yu Yang, Ya Feng Li, Xiao Bing Cui, Xiao Li Zhao, Chuan Bi Li

^*此作品的通讯作者

Jilin University

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

The title compound [Co(en)₃][Co(en)₂(H₂O)₂]₂ • [Mo^V₄Mo^VI₄V^IV ₈O₄₀(AsO₄)] was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is a tetracapped Keggin polyanion, which contains different coordinated cations. The crystal is monoclinic, space group C2/c with a=1.458 3(2) nm, b=2.174 07(13) nm, c=1.893 2(2) nm, β= 91.532°, V=6.000 2(10) nm³, Z=2, A=1.452 g/cm³, R=0.035 9, R_w= 0.079 8, S=1.092.

源语言	英语
页（从-至）	1802
页数	1
期刊	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
卷	22
期	11
出版状态	已出版 - 11月 2001
已对外发布	是

其它文件与链接

链接到 Scopus 的出版物

引用此

Zeng, Q. X., Xu, J. Q., Yang, G. Y., Li, Y. F., Cui, X. B., Zhao, X. L., & Li, C. B. (2001). Synthesis and Structure of a Tetracapped Keggin Polyarsenomolybdovanadate [Co(en)₃][Co(en)₂(H₂O)₂]₂ • [Mo^V₄Mo^VI₄V^IV ₈O₄₀(AsO₄)] Containing Different Coordinated Cations. Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 22(11), 1802.

@article{64c8817cee23489f9924900700915a40,

title = "Synthesis and Structure of a Tetracapped Keggin Polyarsenomolybdovanadate [Co(en)3][Co(en)2(H2O)2]2 • [MoV4MoVI4VIV 8O40(AsO4)] Containing Different Coordinated Cations",

abstract = "The title compound [Co(en)3][Co(en)2(H2O)2]2 • [MoV4MoVI4VIV 8O40(AsO4)] was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is a tetracapped Keggin polyanion, which contains different coordinated cations. The crystal is monoclinic, space group C2/c with a=1.458 3(2) nm, b=2.174 07(13) nm, c=1.893 2(2) nm, β= 91.532°, V=6.000 2(10) nm3, Z=2, A=1.452 g/cm3, R=0.035 9, Rw= 0.079 8, S=1.092.",

keywords = "Crystal structure, Hydrothermal synthesis, Tetracapped Keggin structure",

author = "Zeng, {Qing Xin} and Xu, {Ji Qing} and Yang, {Guo Yu} and Li, {Ya Feng} and Cui, {Xiao Bing} and Zhao, {Xiao Li} and Li, {Chuan Bi}",

year = "2001",

month = nov,

language = "English",

volume = "22",

pages = "1802",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "11",

}

Synthesis and Structure of a Tetracapped Keggin Polyarsenomolybdovanadate [Co(en)₃][Co(en)₂(H₂O)₂]₂ • [Mo^V₄Mo^VI₄V^IV ₈O₄₀(AsO₄)] Containing Different Coordinated Cations. / Zeng, Qing Xin; Xu, Ji Qing; Yang, Guo Yu 等.
在: Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 卷 22, 号码 11, 11.2001, 页码 1802.

科研成果: 期刊稿件 › 文章 › 同行评审

TY - JOUR

T1 - Synthesis and Structure of a Tetracapped Keggin Polyarsenomolybdovanadate [Co(en)3][Co(en)2(H2O)2]2 • [MoV4MoVI4VIV 8O40(AsO4)] Containing Different Coordinated Cations

AU - Zeng, Qing Xin

AU - Xu, Ji Qing

AU - Yang, Guo Yu

AU - Li, Ya Feng

AU - Cui, Xiao Bing

AU - Zhao, Xiao Li

AU - Li, Chuan Bi

PY - 2001/11

Y1 - 2001/11

N2 - The title compound [Co(en)3][Co(en)2(H2O)2]2 • [MoV4MoVI4VIV 8O40(AsO4)] was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is a tetracapped Keggin polyanion, which contains different coordinated cations. The crystal is monoclinic, space group C2/c with a=1.458 3(2) nm, b=2.174 07(13) nm, c=1.893 2(2) nm, β= 91.532°, V=6.000 2(10) nm3, Z=2, A=1.452 g/cm3, R=0.035 9, Rw= 0.079 8, S=1.092.

AB - The title compound [Co(en)3][Co(en)2(H2O)2]2 • [MoV4MoVI4VIV 8O40(AsO4)] was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is a tetracapped Keggin polyanion, which contains different coordinated cations. The crystal is monoclinic, space group C2/c with a=1.458 3(2) nm, b=2.174 07(13) nm, c=1.893 2(2) nm, β= 91.532°, V=6.000 2(10) nm3, Z=2, A=1.452 g/cm3, R=0.035 9, Rw= 0.079 8, S=1.092.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Tetracapped Keggin structure

UR - http://www.scopus.com/inward/record.url?scp=0347118863&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0347118863

SN - 0251-0790

VL - 22

SP - 1802

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 11

ER -

Synthesis and Structure of a Tetracapped Keggin Polyarsenomolybdovanadate [Co(en)3][Co(en)2(H2O)2]2 • [MoV4MoVI4VIV 8O40(AsO4)] Containing Different Coordinated Cations

摘要

其它文件与链接

指纹

引用此

Synthesis and Structure of a Tetracapped Keggin Polyarsenomolybdovanadate [Co(en)₃][Co(en)₂(H₂O)₂]₂ • [Mo^V₄Mo^VI₄V^IV ₈O₄₀(AsO₄)] Containing Different Coordinated Cations