TY - JOUR
T1 - Synthesis and infrared spectroscopic study of 1-D magnetic chain compound based on [BrBzPy][Ni(dmit)2]
AU - Chen, You Cun
AU - Shu, Qing Hai
PY - 2006/1
Y1 - 2006/1
N2 - The synthesis and functional study of one-dimensional free radical-metal chain compound has been a hotspot task in molecule material, especially in composing high Tc molecule ferromagnet. A new compound [BrBzPy] [Ni(dmit)2] has been prepared and characterized. The crystal structure at room temperature was determined. The crystal is triclinic with space group P21/c a = 0.6275(1) ran, b = 1.7438(3) nm, c = 2.2839(3) ran, α = 90°, β = 91.87(1)°, γ = 90°, V = 2.497(7) nm3, Z = 4, Mr = 700.57, and Dc = 1.863 g·cm-3. The planar [Ni(dmit)2]- is nearly perfect, which shows that it has good conjugate characteristic and is a 1-D magnetic chain compound.
AB - The synthesis and functional study of one-dimensional free radical-metal chain compound has been a hotspot task in molecule material, especially in composing high Tc molecule ferromagnet. A new compound [BrBzPy] [Ni(dmit)2] has been prepared and characterized. The crystal structure at room temperature was determined. The crystal is triclinic with space group P21/c a = 0.6275(1) ran, b = 1.7438(3) nm, c = 2.2839(3) ran, α = 90°, β = 91.87(1)°, γ = 90°, V = 2.497(7) nm3, Z = 4, Mr = 700.57, and Dc = 1.863 g·cm-3. The planar [Ni(dmit)2]- is nearly perfect, which shows that it has good conjugate characteristic and is a 1-D magnetic chain compound.
KW - Dmit
KW - Infrared spectra
KW - Molecular magnets
KW - Structure characterization
UR - http://www.scopus.com/inward/record.url?scp=32844464080&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:32844464080
SN - 1000-0593
VL - 26
SP - 54
EP - 56
JO - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis
JF - Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis
IS - 1
ER -