TY - JOUR
T1 - Synthesis and crystal structure of 2,2',5,5'-tetrachloro-1,1'-azo-1,3,4-triazole
AU - Li, Sheng Hua
AU - Shi, Hong Gang
AU - Sun, Cheng Hui
AU - Li, Xiao Tang
AU - Pang, Si Ping
AU - Yu, Yong Zhong
AU - Zhao, Xin Qi
PY - 2009/2
Y1 - 2009/2
N2 - 2,2',5,5'-tetrachloro-1,1'-azo-1,3,4-triazole (1) was synthesized by reaction of 4-amino-1,2,4-triazole and sodium dichloroisocyanurate( SDCI). Its structure was determined by X-ray single crystal diffraction. It crystallizes in the triclinicspace group P-1, with a = 6.2824 (13) Å, b =7.7173(15) Å3, c = 10.443(2) Å, α=89. 16(3) °, β=88.20(3) °, γ= 89.10(3)°, V = 505.94(18) Å3, Z = 2, Mr=301.92, Dc=1.982 mg · m-3, F(000) =296 and μ(MoKα) = 1.152 mm-1, the final R =0.0498 and ωR =0.1139. X-ray analysis reveals that a stronger IT interaction of the triazole units with the tetrazene moiety.
AB - 2,2',5,5'-tetrachloro-1,1'-azo-1,3,4-triazole (1) was synthesized by reaction of 4-amino-1,2,4-triazole and sodium dichloroisocyanurate( SDCI). Its structure was determined by X-ray single crystal diffraction. It crystallizes in the triclinicspace group P-1, with a = 6.2824 (13) Å, b =7.7173(15) Å3, c = 10.443(2) Å, α=89. 16(3) °, β=88.20(3) °, γ= 89.10(3)°, V = 505.94(18) Å3, Z = 2, Mr=301.92, Dc=1.982 mg · m-3, F(000) =296 and μ(MoKα) = 1.152 mm-1, the final R =0.0498 and ωR =0.1139. X-ray analysis reveals that a stronger IT interaction of the triazole units with the tetrazene moiety.
KW - 2,2',5,5'-tetrachloro-1, 1'-azo-1,3,4-triazole
KW - Crystal structure
KW - Nitrogen-rich compound
KW - Organic chemisty
KW - Synthesis
UR - http://www.scopus.com/inward/record.url?scp=62849105652&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:62849105652
SN - 1006-9941
VL - 17
SP - 7
EP - 10
JO - Hanneng Cailiao/Chinese Journal of Energetic Materials
JF - Hanneng Cailiao/Chinese Journal of Energetic Materials
IS - 1
ER -