TY - JOUR
T1 - Synthesis and characterization of heterobimetallic aluminum-germanium(IV) disulfides
AU - Yang, Zhi
AU - Ma, Xiaoli
AU - Zhang, Zhensheng
AU - Roesky, Herbert W.
AU - Magull, Jörg
AU - Ringe, Arne
PY - 2008/12
Y1 - 2008/12
N2 - Three heterobimetallic aluminum-germanium(IV) disulfides are synthesized. The reaction of {LAl[(SLi)2(THF)2]}2 (1) (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) with Ph2GeCl2, Me2GeCl2, and GeCl 4, respectively, in THF afforded LAl(μ-S)2GePh 2 (2), LAl(μ-S)2GeMe2 (3) and LAl(μ-S)2Ge(μ-S)2AlL (4) in good yields. Compounds 2, 3 and 4 were investigated by elemental analysis, NMR, EI-MS and 3 was also characterized by single crystal X-ray structural analysis.
AB - Three heterobimetallic aluminum-germanium(IV) disulfides are synthesized. The reaction of {LAl[(SLi)2(THF)2]}2 (1) (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) with Ph2GeCl2, Me2GeCl2, and GeCl 4, respectively, in THF afforded LAl(μ-S)2GePh 2 (2), LAl(μ-S)2GeMe2 (3) and LAl(μ-S)2Ge(μ-S)2AlL (4) in good yields. Compounds 2, 3 and 4 were investigated by elemental analysis, NMR, EI-MS and 3 was also characterized by single crystal X-ray structural analysis.
KW - Aluminum
KW - Disulfides
KW - Germanium
KW - Heterobimetallic compounds
UR - http://www.scopus.com/inward/record.url?scp=57349106487&partnerID=8YFLogxK
U2 - 10.1002/zaac.200800030
DO - 10.1002/zaac.200800030
M3 - Article
AN - SCOPUS:57349106487
SN - 0044-2313
VL - 634
SP - 2740
EP - 2742
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 15
ER -