Synthesis and characterization of diazidoglyoxime

Xiao Jun Wang; Qiang Su; Guang Yuan Zhang; Xia Wang; Jun Feng Wang

doi:10.11943/j.issn.1006-9941.2014.06.005

Synthesis and characterization of diazidoglyoxime

Xiao Jun Wang, Qiang Su, Guang Yuan Zhang, Xia Wang, Jun Feng Wang

材料学院

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

Diazidoglyoxime was synthesized using solution glyoxal (40% w/w in H₂O) and hydroxylammonium as starting materials through substitution, chloration and nitrine reaction. Its structure was characterized by IR, elemental analysis and NMR. Results show that the impact sensitivity H₅₀ is 17.5 cm, and the friction sensitivity is 36%. Based on the study of effects of the nitrine reaction, the optimal reaction conditions were determined as following: reaction medium is dimethyl formamide, reaction temperature 0℃, and the yied of nitrine reaction 81.3%.

源语言	英语
页（从-至）	741-743
页数	3
期刊	Hanneng Cailiao/Chinese Journal of Energetic Materials
卷	22
期	6
DOI	https://doi.org/10.11943/j.issn.1006-9941.2014.06.005
出版状态	已出版 - 25 12月 2014

访问文件

10.11943/j.issn.1006-9941.2014.06.005

其它文件与链接

链接到 Scopus 的出版物

引用此

Wang, X. J., Su, Q., Zhang, G. Y., Wang, X., & Wang, J. F. (2014). Synthesis and characterization of diazidoglyoxime. Hanneng Cailiao/Chinese Journal of Energetic Materials, 22(6), 741-743. https://doi.org/10.11943/j.issn.1006-9941.2014.06.005

@article{5e4584ba5ae147e4bfa95f10007492fc,

title = "Synthesis and characterization of diazidoglyoxime",

abstract = "Diazidoglyoxime was synthesized using solution glyoxal (40% w/w in H2O) and hydroxylammonium as starting materials through substitution, chloration and nitrine reaction. Its structure was characterized by IR, elemental analysis and NMR. Results show that the impact sensitivity H50 is 17.5 cm, and the friction sensitivity is 36%. Based on the study of effects of the nitrine reaction, the optimal reaction conditions were determined as following: reaction medium is dimethyl formamide, reaction temperature 0℃, and the yied of nitrine reaction 81.3%.",

keywords = "Diazidoglyoxime, Energetic materials, Organic chemistry, Synthesis",

author = "Wang, {Xiao Jun} and Qiang Su and Zhang, {Guang Yuan} and Xia Wang and Wang, {Jun Feng}",

year = "2014",

month = dec,

day = "25",

doi = "10.11943/j.issn.1006-9941.2014.06.005",

language = "English",

volume = "22",

pages = "741--743",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "6",

}

TY - JOUR

T1 - Synthesis and characterization of diazidoglyoxime

AU - Wang, Xiao Jun

AU - Su, Qiang

AU - Zhang, Guang Yuan

AU - Wang, Xia

AU - Wang, Jun Feng

PY - 2014/12/25

Y1 - 2014/12/25

N2 - Diazidoglyoxime was synthesized using solution glyoxal (40% w/w in H2O) and hydroxylammonium as starting materials through substitution, chloration and nitrine reaction. Its structure was characterized by IR, elemental analysis and NMR. Results show that the impact sensitivity H50 is 17.5 cm, and the friction sensitivity is 36%. Based on the study of effects of the nitrine reaction, the optimal reaction conditions were determined as following: reaction medium is dimethyl formamide, reaction temperature 0℃, and the yied of nitrine reaction 81.3%.

AB - Diazidoglyoxime was synthesized using solution glyoxal (40% w/w in H2O) and hydroxylammonium as starting materials through substitution, chloration and nitrine reaction. Its structure was characterized by IR, elemental analysis and NMR. Results show that the impact sensitivity H50 is 17.5 cm, and the friction sensitivity is 36%. Based on the study of effects of the nitrine reaction, the optimal reaction conditions were determined as following: reaction medium is dimethyl formamide, reaction temperature 0℃, and the yied of nitrine reaction 81.3%.

KW - Diazidoglyoxime

KW - Energetic materials

KW - Organic chemistry

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=84922249199&partnerID=8YFLogxK

U2 - 10.11943/j.issn.1006-9941.2014.06.005

DO - 10.11943/j.issn.1006-9941.2014.06.005

M3 - Article

AN - SCOPUS:84922249199

SN - 1006-9941

VL - 22

SP - 741

EP - 743

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 6

ER -

Synthesis and characterization of diazidoglyoxime

摘要

访问文件

其它文件与链接

指纹

引用此