摘要
A new lead borate, Pb[B8O11(OH)4], has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction, FTIR, powder X-ray diffraction and thermogravimetric analysis. The compound crystallizes in the monoclinic system, space group P21/n (No. 14), a=7.9081(2)Å, b=14.0248(3)Å, c=9.9910(3)Å, β=90.327(2)°, V=1108.08(5)Å3, and Z=4. The structure consists of layers of 9-membered borate rings enclosing Pb 2+ cations. Adjacent borate layers are interconnected via ionic Pb-O bonds and hydrogen bonding to form a 3D supramolecular network.
源语言 | 英语 |
---|---|
页(从-至) | 398-403 |
页数 | 6 |
期刊 | Journal of Solid State Chemistry |
卷 | 179 |
期 | 2 |
DOI | |
出版状态 | 已出版 - 2月 2006 |
已对外发布 | 是 |
指纹
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Wang, G. M., Sun, Y. Q., & Yang, G. Y. (2006). Synthesis and characterization of a new layered lead borate. Journal of Solid State Chemistry, 179(2), 398-403. https://doi.org/10.1016/j.jssc.2005.10.034