TY - JOUR
T1 - Synthesis and characterization of a new layered lead borate
AU - Wang, Guo Ming
AU - Sun, Yan Qiong
AU - Yang, Guo Yu
PY - 2006/2
Y1 - 2006/2
N2 - A new lead borate, Pb[B8O11(OH)4], has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction, FTIR, powder X-ray diffraction and thermogravimetric analysis. The compound crystallizes in the monoclinic system, space group P21/n (No. 14), a=7.9081(2)Å, b=14.0248(3)Å, c=9.9910(3)Å, β=90.327(2)°, V=1108.08(5)Å3, and Z=4. The structure consists of layers of 9-membered borate rings enclosing Pb 2+ cations. Adjacent borate layers are interconnected via ionic Pb-O bonds and hydrogen bonding to form a 3D supramolecular network.
AB - A new lead borate, Pb[B8O11(OH)4], has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction, FTIR, powder X-ray diffraction and thermogravimetric analysis. The compound crystallizes in the monoclinic system, space group P21/n (No. 14), a=7.9081(2)Å, b=14.0248(3)Å, c=9.9910(3)Å, β=90.327(2)°, V=1108.08(5)Å3, and Z=4. The structure consists of layers of 9-membered borate rings enclosing Pb 2+ cations. Adjacent borate layers are interconnected via ionic Pb-O bonds and hydrogen bonding to form a 3D supramolecular network.
KW - Borates
KW - Crystal structure
KW - Hydrothermal synthesis
KW - Lead borate
UR - http://www.scopus.com/inward/record.url?scp=31044435732&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2005.10.034
DO - 10.1016/j.jssc.2005.10.034
M3 - Article
AN - SCOPUS:31044435732
SN - 0022-4596
VL - 179
SP - 398
EP - 403
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
IS - 2
ER -