Syntheses, crystal structures and thermal analyses of two new ionic complexes based on 3,4-diamino-1,2,4-triazole

Jin Ting Wu; Jian Guo Zhang; Xin Jin; Xin Yin; Tong Lai Zhang

doi:10.1080/00958972.2016.1160378

Syntheses, crystal structures and thermal analyses of two new ionic complexes based on 3,4-diamino-1,2,4-triazole

Jin Ting Wu, Jian Guo Zhang^*, Xin Jin, Xin Yin, Tong Lai Zhang

^*此作品的通讯作者

机电学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

Two new ionic complexes, (DATr)₂[Li₂(TNR)₂·2H₂O]·2H₂O (1) and (DATr)[Zn(DATr)Cl₃] (2), were synthesized by using 3,4-diamino-1,2,4-triazole (DATr) as outer cation. X-ray single-crystal diffraction analysis revealed that the two complexes crystallize in triclinic and orthorhombic crystal systems, respectively. Differential scanning calorimetry was applied to assess the thermal decomposition behavior and kinetic parameters of decomposition were studied by using Kissingers and Ozawa-Doyles methods. Furthermore, the critical temperature of thermal explosion and parameters of thermodynamics were obtained. (Chemical Equation Presented).

源语言	英语
页（从-至）	1236-1243
页数	8
期刊	Journal of Coordination Chemistry
卷	69
期	7
DOI	https://doi.org/10.1080/00958972.2016.1160378
出版状态	已出版 - 2016

访问文件

10.1080/00958972.2016.1160378

其它文件与链接

链接到 Scopus 的出版物

引用此

Wu, J. T., Zhang, J. G., Jin, X., Yin, X., & Zhang, T. L. (2016). Syntheses, crystal structures and thermal analyses of two new ionic complexes based on 3,4-diamino-1,2,4-triazole. Journal of Coordination Chemistry, 69(7), 1236-1243. https://doi.org/10.1080/00958972.2016.1160378

@article{cb04b16c271c48c7a3ca48bf4d3534b2,

title = "Syntheses, crystal structures and thermal analyses of two new ionic complexes based on 3,4-diamino-1,2,4-triazole",

abstract = "Two new ionic complexes, (DATr)2[Li2(TNR)2·2H2O]·2H2O (1) and (DATr)[Zn(DATr)Cl3] (2), were synthesized by using 3,4-diamino-1,2,4-triazole (DATr) as outer cation. X-ray single-crystal diffraction analysis revealed that the two complexes crystallize in triclinic and orthorhombic crystal systems, respectively. Differential scanning calorimetry was applied to assess the thermal decomposition behavior and kinetic parameters of decomposition were studied by using Kissingers and Ozawa-Doyles methods. Furthermore, the critical temperature of thermal explosion and parameters of thermodynamics were obtained. (Chemical Equation Presented).",

keywords = "3,4-diamino-1,2,4-triazole, Complexes, crystal structure, thermal analysis",

author = "Wu, {Jin Ting} and Zhang, {Jian Guo} and Xin Jin and Xin Yin and Zhang, {Tong Lai}",

note = "Publisher Copyright: {\textcopyright} 2016 Informa UK Limited, trading as Taylor & Francis Group.",

year = "2016",

doi = "10.1080/00958972.2016.1160378",

language = "English",

volume = "69",

pages = "1236--1243",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "7",

}

TY - JOUR

T1 - Syntheses, crystal structures and thermal analyses of two new ionic complexes based on 3,4-diamino-1,2,4-triazole

AU - Wu, Jin Ting

AU - Zhang, Jian Guo

AU - Jin, Xin

AU - Yin, Xin

AU - Zhang, Tong Lai

PY - 2016

Y1 - 2016

N2 - Two new ionic complexes, (DATr)2[Li2(TNR)2·2H2O]·2H2O (1) and (DATr)[Zn(DATr)Cl3] (2), were synthesized by using 3,4-diamino-1,2,4-triazole (DATr) as outer cation. X-ray single-crystal diffraction analysis revealed that the two complexes crystallize in triclinic and orthorhombic crystal systems, respectively. Differential scanning calorimetry was applied to assess the thermal decomposition behavior and kinetic parameters of decomposition were studied by using Kissingers and Ozawa-Doyles methods. Furthermore, the critical temperature of thermal explosion and parameters of thermodynamics were obtained. (Chemical Equation Presented).

AB - Two new ionic complexes, (DATr)2[Li2(TNR)2·2H2O]·2H2O (1) and (DATr)[Zn(DATr)Cl3] (2), were synthesized by using 3,4-diamino-1,2,4-triazole (DATr) as outer cation. X-ray single-crystal diffraction analysis revealed that the two complexes crystallize in triclinic and orthorhombic crystal systems, respectively. Differential scanning calorimetry was applied to assess the thermal decomposition behavior and kinetic parameters of decomposition were studied by using Kissingers and Ozawa-Doyles methods. Furthermore, the critical temperature of thermal explosion and parameters of thermodynamics were obtained. (Chemical Equation Presented).

KW - 3,4-diamino-1,2,4-triazole

KW - Complexes

KW - crystal structure

KW - thermal analysis

UR - http://www.scopus.com/inward/record.url?scp=84961216101&partnerID=8YFLogxK

U2 - 10.1080/00958972.2016.1160378

DO - 10.1080/00958972.2016.1160378

M3 - Article

AN - SCOPUS:84961216101

SN - 0095-8972

VL - 69

SP - 1236

EP - 1243

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 7

ER -

Syntheses, crystal structures and thermal analyses of two new ionic complexes based on 3,4-diamino-1,2,4-triazole

摘要

访问文件

其它文件与链接

指纹

引用此