Response to Comment on "Synthesis and characterization of the pentazolate anion cyclo-N5- in (N5)6(H3O)3(NH4)4Cl"

Chao Jiang; Lei Zhang; Chengguo Sun; Chong Zhang; Chen Yang; Jun Chen; Bingcheng Hu

doi:10.1126/science.aas8953

Response to Comment on "Synthesis and characterization of the pentazolate anion cyclo-N₅^- in (N₅)₆(H3O)₃(NH₄)₄Cl"

Chao Jiang, Lei Zhang, Chengguo Sun, Chong Zhang, Chen Yang, Jun Chen^*, Bingcheng Hu

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31 引用（Scopus）

摘要

Huang and Xu argue that the cyclo-N₅^- ion in (N₅)₆(H₃O)₃(NH₄)₄Cl we described in our report is theoretically unfavorable and is instead protonated. Their conclusion is invalid, as they use an improper method to assess the proton transfer in a solid crystal structure. We present an in-depth experimental and theoretical analysis of (N₅)₆(H₃O)₃(NH₄)₄Cl that supports the results in the original paper.

源语言	英语
文章编号	aas8953
期刊	Science
卷	359
期	6381
DOI	https://doi.org/10.1126/science.aas8953
出版状态	已出版 - 16 3月 2018
已对外发布	是

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title = "Response to Comment on {"}Synthesis and characterization of the pentazolate anion cyclo-N5- in (N5)6(H3O)3(NH4)4Cl{"}",

abstract = "Huang and Xu argue that the cyclo-N5- ion in (N5)6(H3O)3(NH4)4Cl we described in our report is theoretically unfavorable and is instead protonated. Their conclusion is invalid, as they use an improper method to assess the proton transfer in a solid crystal structure. We present an in-depth experimental and theoretical analysis of (N5)6(H3O)3(NH4)4Cl that supports the results in the original paper.",

author = "Chao Jiang and Lei Zhang and Chengguo Sun and Chong Zhang and Chen Yang and Jun Chen and Bingcheng Hu",

note = "Publisher Copyright: {\textcopyright} 2017 The Authors, some rights reserved.",

year = "2018",

month = mar,

day = "16",

doi = "10.1126/science.aas8953",

language = "English",

volume = "359",

journal = "Science",

issn = "0036-8075",

publisher = "American Association for the Advancement of Science",

number = "6381",

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TY - JOUR

T1 - Response to Comment on "Synthesis and characterization of the pentazolate anion cyclo-N5- in (N5)6(H3O)3(NH4)4Cl"

AU - Jiang, Chao

AU - Zhang, Lei

AU - Sun, Chengguo

AU - Zhang, Chong

AU - Yang, Chen

AU - Chen, Jun

AU - Hu, Bingcheng

PY - 2018/3/16

Y1 - 2018/3/16

N2 - Huang and Xu argue that the cyclo-N5- ion in (N5)6(H3O)3(NH4)4Cl we described in our report is theoretically unfavorable and is instead protonated. Their conclusion is invalid, as they use an improper method to assess the proton transfer in a solid crystal structure. We present an in-depth experimental and theoretical analysis of (N5)6(H3O)3(NH4)4Cl that supports the results in the original paper.

AB - Huang and Xu argue that the cyclo-N5- ion in (N5)6(H3O)3(NH4)4Cl we described in our report is theoretically unfavorable and is instead protonated. Their conclusion is invalid, as they use an improper method to assess the proton transfer in a solid crystal structure. We present an in-depth experimental and theoretical analysis of (N5)6(H3O)3(NH4)4Cl that supports the results in the original paper.

UR - http://www.scopus.com/inward/record.url?scp=85043979613&partnerID=8YFLogxK

U2 - 10.1126/science.aas8953

DO - 10.1126/science.aas8953

M3 - Article

C2 - 29590050

AN - SCOPUS:85043979613

SN - 0036-8075

VL - 359

JO - Science

JF - Science

IS - 6381

M1 - aas8953

ER -

Response to Comment on "Synthesis and characterization of the pentazolate anion cyclo-N5- in (N5)6(H3O)3(NH4)4Cl"

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Response to Comment on "Synthesis and characterization of the pentazolate anion cyclo-N₅^- in (N₅)₆(H3O)₃(NH₄)₄Cl"