TY - JOUR
T1 - Reduction of carbodiimides by a dialumane through insertion and cycloaddition
AU - Xiao, Lin
AU - Chen, Weixing
AU - Shen, Lingyi
AU - Liu, Li
AU - Xue, Yujie
AU - Zhao, Yanxia
AU - Yang, Xiao Juan
N1 - Publisher Copyright:
© The Royal Society of Chemistry 2020.
PY - 2020/6/14
Y1 - 2020/6/14
N2 - The dialumane [L2−AlII-AlIIL2−] (L = [(2,6-iPr2C6H3)NC(Me)]2; 1) reacts with carbodiimides, RN-C-NR (R = Cy, iPr), through insertion, [2+4] cycloaddition, and a hydrogen transfer process. However, with the bulkier carbodiimides (R = dipp = 2,6-iPr2C6H3,tBu), the reactions are sterically controlled and lead to the formamidinate products.
AB - The dialumane [L2−AlII-AlIIL2−] (L = [(2,6-iPr2C6H3)NC(Me)]2; 1) reacts with carbodiimides, RN-C-NR (R = Cy, iPr), through insertion, [2+4] cycloaddition, and a hydrogen transfer process. However, with the bulkier carbodiimides (R = dipp = 2,6-iPr2C6H3,tBu), the reactions are sterically controlled and lead to the formamidinate products.
UR - http://www.scopus.com/inward/record.url?scp=85086332034&partnerID=8YFLogxK
U2 - 10.1039/d0cc02048f
DO - 10.1039/d0cc02048f
M3 - Article
C2 - 32390025
AN - SCOPUS:85086332034
SN - 1359-7345
VL - 56
SP - 6352
EP - 6355
JO - Chemical Communications
JF - Chemical Communications
IS - 47
ER -