Nitroxide-mediated free radical synthesis of mesogen-jacketed liquid crystal polymers

Xin Hua Wan; Hui Lin Tu; Ying Feng Tu; Dong Zhang; Ling Sun; Qi Feng Zhou; Yu Ping Dong; Mao Tang

Nitroxide-mediated free radical synthesis of mesogen-jacketed liquid crystal polymers

Xin Hua Wan^*, Hui Lin Tu, Ying Feng Tu, Dong Zhang, Ling Sun, Qi Feng Zhou, Yu Ping Dong, Mao Tang

^*此作品的通讯作者

材料学院

科研成果: 期刊稿件 › 文章 › 同行评审

22 引用（Scopus）

摘要

The first TEMPO-mediated "living" free radical polymerization of liquid crystalline monomer, 2, 5-bis[(4-methoxyphenyl)oxycarbonyl]styrene (MFCS), was carried out at 130°C with BPO as an initiator. The molecular weight of the polymer can be varied from rather low values to high values while maintaining narrow polydispersity. It was observed that the polymerization of MFCS proceeded much faster than that of styrene. A tentative explanation for this fast polymerization was suggested.

源语言	英语
页（从-至）	189-192
页数	4
期刊	Chinese Journal of Polymer Science (English Edition)
卷	17
期	2
出版状态	已出版 - 1999

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abstract = "The first TEMPO-mediated {"}living{"} free radical polymerization of liquid crystalline monomer, 2, 5-bis[(4-methoxyphenyl)oxycarbonyl]styrene (MFCS), was carried out at 130°C with BPO as an initiator. The molecular weight of the polymer can be varied from rather low values to high values while maintaining narrow polydispersity. It was observed that the polymerization of MFCS proceeded much faster than that of styrene. A tentative explanation for this fast polymerization was suggested.",

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author = "Wan, {Xin Hua} and Tu, {Hui Lin} and Tu, {Ying Feng} and Dong Zhang and Ling Sun and Zhou, {Qi Feng} and Dong, {Yu Ping} and Mao Tang",

year = "1999",

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T1 - Nitroxide-mediated free radical synthesis of mesogen-jacketed liquid crystal polymers

AU - Wan, Xin Hua

AU - Tu, Hui Lin

AU - Tu, Ying Feng

AU - Zhang, Dong

AU - Sun, Ling

AU - Zhou, Qi Feng

AU - Dong, Yu Ping

AU - Tang, Mao

PY - 1999

Y1 - 1999

N2 - The first TEMPO-mediated "living" free radical polymerization of liquid crystalline monomer, 2, 5-bis[(4-methoxyphenyl)oxycarbonyl]styrene (MFCS), was carried out at 130°C with BPO as an initiator. The molecular weight of the polymer can be varied from rather low values to high values while maintaining narrow polydispersity. It was observed that the polymerization of MFCS proceeded much faster than that of styrene. A tentative explanation for this fast polymerization was suggested.

AB - The first TEMPO-mediated "living" free radical polymerization of liquid crystalline monomer, 2, 5-bis[(4-methoxyphenyl)oxycarbonyl]styrene (MFCS), was carried out at 130°C with BPO as an initiator. The molecular weight of the polymer can be varied from rather low values to high values while maintaining narrow polydispersity. It was observed that the polymerization of MFCS proceeded much faster than that of styrene. A tentative explanation for this fast polymerization was suggested.

KW - "living" free radical polymerization

KW - Mesogen-jacketed liquid crystal polymer

KW - Mesophase polymerization

KW - TEMPO

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M3 - Article

AN - SCOPUS:22644448856

SN - 0256-7679

VL - 17

SP - 189

EP - 192

JO - Chinese Journal of Polymer Science (English Edition)

JF - Chinese Journal of Polymer Science (English Edition)

IS - 2

ER -

Nitroxide-mediated free radical synthesis of mesogen-jacketed liquid crystal polymers

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