New Pb-Pb bonds: Syntheses and molecular structures of hexabiphenyldiplumbane and tri(trisbiphenylplumbyl)plumbate

Yuzhong Wang; Brandon Quillian; Pingrong Wei; Xiao Juan Yang; Gregory H. Robinson

doi:10.1039/b408860n

New Pb-Pb bonds: Syntheses and molecular structures of hexabiphenyldiplumbane and tri(trisbiphenylplumbyl)plumbate

Yuzhong Wang, Brandon Quillian, Pingrong Wei, Xiao Juan Yang, Gregory H. Robinson^*

^*此作品的通讯作者

University of Georgia

科研成果: 期刊稿件 › 文章 › 同行评审

21 引用（Scopus）

摘要

Reaction of lead(II) chloride with biphenylmagnesium bromide yields Bp ₃Pb-PbBp₃ and [(THF)₃Mg(μ-Cl) ₃Mg(THF)₃]-[Pb(PbBp₃)₃] (Bp = biphenyl), which, upon single crystal X-ray crystallographic analysis, reveals an interesting variation of Pb-Pb bond distances.

源语言	英语
页（从-至）	2224-2225
页数	2
期刊	Chemical Communications
期	19
DOI	https://doi.org/10.1039/b408860n
出版状态	已出版 - 7 11月 2004
已对外发布	是

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abstract = "Reaction of lead(II) chloride with biphenylmagnesium bromide yields Bp 3Pb-PbBp3 and [(THF)3Mg(μ-Cl) 3Mg(THF)3]-[Pb(PbBp3)3] (Bp = biphenyl), which, upon single crystal X-ray crystallographic analysis, reveals an interesting variation of Pb-Pb bond distances.",

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AU - Quillian, Brandon

AU - Wei, Pingrong

AU - Yang, Xiao Juan

AU - Robinson, Gregory H.

PY - 2004/11/7

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N2 - Reaction of lead(II) chloride with biphenylmagnesium bromide yields Bp 3Pb-PbBp3 and [(THF)3Mg(μ-Cl) 3Mg(THF)3]-[Pb(PbBp3)3] (Bp = biphenyl), which, upon single crystal X-ray crystallographic analysis, reveals an interesting variation of Pb-Pb bond distances.

AB - Reaction of lead(II) chloride with biphenylmagnesium bromide yields Bp 3Pb-PbBp3 and [(THF)3Mg(μ-Cl) 3Mg(THF)3]-[Pb(PbBp3)3] (Bp = biphenyl), which, upon single crystal X-ray crystallographic analysis, reveals an interesting variation of Pb-Pb bond distances.

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New Pb-Pb bonds: Syntheses and molecular structures of hexabiphenyldiplumbane and tri(trisbiphenylplumbyl)plumbate

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