Measurements of conductivity for low concentration strongelectrolytes in organic solvents (I) LiBr, LiCl, and LiNO3 in alcohols

Hong Chen, Lisheng Wang*, Bo Jiang, Miyi Li

*此作品的通讯作者

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9 引用 (Scopus)

摘要

The conductivities of LiBr, LiCl, and LiNO3 in methanol, ethanol, 1-propanol, and 2-propanol (with electrolyte concentrations <0.08 mol·L-1) were determined at 298.15 K, 313.15 K, and 323.15 K at atmosphere pressure separately by using a conductivity meter. The conductivity data were correlated with Foss-Chen-Justice (FCJ) equation and the limiting molar conductivities were obtained. The mean ionic activity coefficients of the salts in the organic solvents were calculated according to the Debye-Huckel limiting law and Onsager-Falkenhangen equations. The calculated results were compared with those activity coefficients in literature.

源语言英语
页(从-至)1024-1033
页数10
期刊Chinese Journal of Chemical Engineering
20
5
DOI
出版状态已出版 - 10月 2012

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